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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Schafler, Erhard
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Verifying the cytotoxicity of a biodegradable zinc alloy with nanodiamond sensorscitations
- 2024Radial dependence of thermal, structural and micro deformation characteristics in Cu-Zr-Al bulk metallic glass subjected to high pressure torsioncitations
- 2024Effect of V content on the microstructure and mechanical properties of HPT nanostructured CoCrFeMnNiV x high entropy alloys
- 2023Comprehensive thermal analysis of a high stability Cu–Zr–Al bulk metallic glass subjected to high-pressure torsioncitations
- 2023From unlikely pairings to functional nanocomposites: FeTi–Cu as a model systemcitations
- 2022Structure-dynamics relationships in cryogenically deformed bulk metallic glasscitations
- 2022Thermal, Microstructural and Electrochemical Hydriding Performance of a Mg65Ni20Cu5Y10 Metallic Glass Catalyzed by CNT and Processed by High-Pressure Torsioncitations
- 2021In Situ Synchrotron X‐Ray Diffraction during High‐Pressure Torsion Deformation of Ni and NiTicitations
- 2021Properties of HPT-Processed Large Bulks of p-Type Skutterudite DD0.7Fe3CoSb12 with ZT > 1.3citations
- 2021Enhancing the Mechanical Properties of Biodegradable Mg Alloys Processed by Warm HPT and Thermal Treatmentscitations
- 2021High-Velocity Stretching of Renewable Polymer Blendscitations
- 2020The effects of severe plastic deformation and/or thermal treatment on the mechanical properties of biodegradable mg-alloyscitations
- 2020Advanced Immersion Testing of Model Mg-Alloys for Biomedical Applicationscitations
- 2020Anomalous Evolution of Strength and Microstructure of High-Entropy Alloy CoCrFeNiMn after High-Pressure Torsion at 300 and 77 Kcitations
- 2017Dislocation Movement Induced by Molecular Relaxations in Isotactic Polypropylenecitations
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article
Properties of HPT-Processed Large Bulks of p-Type Skutterudite DD0.7Fe3CoSb12 with ZT > 1.3
Abstract
<p>The influence of shear strain on the microstructural, physical, and mechanical properties was studied on large bulk samples (diameter: 30 mm, thickness: 1 or 8 mm), which were consolidated by high-pressure torsion (HPT) from a commercial powder DD0.7Fe3CoSb12. Particularly, the thick sample (mass similar to 53 g) allowed measuring the thermoelectric (TE) properties with respect to various orientations of the specimen in the sample. All data were compared with those of a hot-pressed (HP) reference sample, prepared with the same powder. Transmission electron microscopy, as well as X-ray powder diffraction profile analyses, Hall measurements, and positron annihilation spectroscopy, supported these investigations. Furthermore, synchrotron data for the temperature range from 300 to 825 K were used to evaluate the changes in the grain size and dislocation density as well as the thermal expansion coefficient via the change in the lattice parameter during heating. In addition, hardness and direct thermal expansion measurements of the HPT samples were performed and compared with the HP reference sample's values. With the increase of the shear strain from the center to the rim of the sample, the electrical resistivity becomes higher, whereas the thermal conductivity becomes lower, but the Seebeck coefficient remained almost unchanged. For the thin as well as thick samples, the enhanced electrical resistivity was balanced out by a decreased thermal conductivity such that the maximum ZT values (ZT = 1.3-1.35 at 856 K) do not vary much as a function of the shear strain throughout the sample, however, all ZTs are higher than that of the HP sample. The thermal-electric conversion efficiencies are in the range of 14-15% (for 423-823 K). With similar high ZT values for the n-type skutterudites, fabricated in the same fast and sustainable way, these p- and n-type skutterudites may serve as legs for TE generators, directly cut from the big HPT bulks.</p>