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Aktekin, Burak
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Publications (7/7 displayed)
- 2024SEI growth on Lithium metal anodes in solid-state batteries quantified with coulometric titration time analysis
- 2023SEI growth on Lithium metal anodes in solid-state batteries quantified with coulometric titration time analysiscitations
- 2022Recycling of All-Solid-State Li-ion Batteries: A Case Study of the Separation of Individual Components Within a System Composed of LTO, LLZTO, and NMC
- 2022Concentrated LiFSI-Ethylene Carbonate Electrolytes and Their Compatibility with High-Capacity and High-Voltage Electrodescitations
- 2020How Mn/Ni Ordering Controls Electrochemical Performance in High-Voltage Spinel LiNi0.44Mn1.56O4 with Fixed Oxygen Contentcitations
- 2020How Mn/Ni Ordering Controls Electrochemical Performance in High-Voltage Spinel LiNi0.44Mn1.56O4with Fixed Oxygen Contentcitations
- 2020How Mn/Ni Ordering Controls Electrochemical Performance in High-Voltage Spinel LiNi 0.44 Mn 1.56 O 4 with Fixed Oxygen Contentcitations
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article
How Mn/Ni Ordering Controls Electrochemical Performance in High-Voltage Spinel LiNi0.44Mn1.56O4with Fixed Oxygen Content
Abstract
<p>The crystal structure of LiNi0.5Mn1.5O4 (LNMO) can adopt either low-symmetry ordered (Fd3¯ m) or high-symmetry disordered (P4332) space group depending on the synthesis conditions. A majority of published studies agree on superior electrochemical performance of disordered LNMO, but the underlying reasons for improvement remain unclear due to the fact that different thermal history of the samples affects other material properties such as oxygen content and particle morphology. In this study, ordered and disordered samples were prepared with a new strategy that renders samples with identical properties apart from their cation ordering degree. This was achieved by heat treatment of powders under pure oxygen atmosphere at high temperature with a final annealing step at 710 °C for both samples, followed by slow or fast cooling. Electrochemical testing showed that cation disordering improves the stability of material in charged (delithiated) state and mitigates the impedance rise in LNMO-1LTO (Li4Ti5O12) and LNMO-1Li cells. Through X-ray photoelectron spectroscopy (XPS), thicker surface films were observed on the ordered material, indicating more electrolyte side reactions. The ordered samples also showed significant changes in the Ni 2p XPS spectra, while the generation of ligand (oxygen) holes was observed in the Ni-O environment for both samples using X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS). Moreover, high-resolution transmission electron microscopy (HRTEM) images indicated that the ordered samples show a decrease in ordering near the particle surface after cycling and a tendency toward rock-salt-like phase transformations. These results show that the structural arrangement of Mn/Ni (alone) has an effect on the surface and "near-surface"properties of LNMO, particularly in delithiated state, which is likely connected to the bulk electronic properties of this electrode material.</p>