| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Race, Christopher P.
University of Sheffield
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Molecular dynamics simulations of neutron induced collision cascades in Zr — Statistical modelling of irradiation damage and potential applicationscitations
- 2024Fractional densities and character of dislocations in different slip modes from powder diffraction patternscitations
- 2023Interaction of monoclinic ZrO2 grain boundaries with oxygen vacancies, Sn and Nb - implications for the corrosion of Zr alloy fuel cladding
- 2023Dislocation density transients and saturation in irradiated zirconiumcitations
- 2023Breakaway Growth Modeling of Zirconium under Irradiation: The Importance of the Formation of a-Loop Layerscitations
- 2022Simulating intergranular hydrogen enhanced decohesion in aluminium using density functional theorycitations
- 2022A novel method for radial hydride analysis in zirconium alloyscitations
- 2022Breakaway Growth Modeling of Zirconium under Irradiation: The Importance of the Formation of a-Loop Layerscitations
- 2021The Importance of Substrate Grain Orientation on Local Oxide Texture and Corrosion Performance in α-Zr Alloyscitations
- 2021The Importance of Substrate Grain Orientation on Local Oxide Texture and Corrosion Performance in α-Zr Alloyscitations
- 2021Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenescitations
- 2020Modelling Hydrogen Embrittlement using Density Functional Theory: A theoretical approach to understanding environmentally assisted cracking in 7xxx series aluminium alloyscitations
- 2019Imaging three-dimensional elemental inhomogeneity in Pt–Ni nanoparticles using spectroscopic single particle reconstructioncitations
- 2019The effect of irradiation temperature on damage structures in proton-irradiated zirconium alloyscitations
- 2018The Effect of Iron on Dislocation Evolution in Model and Commercial Zirconium Alloyscitations
- 2018Advanced 3D characterisation of iodine induced stress corrosion cracks in zirconium alloyscitations
- 2017Investigating the thermal stability of irradiation-induced damage in a zirconium alloy with novel in situ techniquescitations
Places of action
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article
Imaging three-dimensional elemental inhomogeneity in Pt–Ni nanoparticles using spectroscopic single particle reconstruction
Abstract
The properties of nanoparticles are known to critically depend on their local chemistry but characterizing three-dimensional (3D) elemental segregation at the nanometer scale is highly challenging. Scanning transmission electron microscope (STEM) tomographic imaging is one of the few techniques able to measure local chemistry for inorganic nanoparticles but conventional methodologies often fail due to the high electron dose imparted. Here, we demonstrate realization of a new spectroscopic single particle reconstruction approach built on a method developed by structural biologists. We apply this technique to the imaging of PtNi nanocatalysts and find new evidence of a complex inhomogeneous alloying with a Pt-rich core, a Ni-rich hollow octahedral intermediate shell and a Pt-rich rhombic dodecahedral skeleton framework with less Pt at ⟨100⟩ vertices. The ability to gain evidence of local surface enrichment that varies with the crystallographic orientation of facets and vertices is expected to provide significant insight toward the development of nanoparticles for sensing, medical imaging, and catalysis.