Materials Map

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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Naji, M.
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Palmans, Ara Anja

  • Google
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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (36/36 displayed)

  • 2024Enhanced Efficiency of Pd(0)-Based Single Chain Polymeric Nanoparticles for in Vitro Prodrug Activation by Modulating the Polymer’s Microstructure10citations
  • 2023Dynamic covalent networks with tunable dynamicity by mixing acylsemicarbazides and thioacylsemicarbazides8citations
  • 2022Elucidating the Stability of Single-Chain Polymeric Nanoparticles in Biological Media and Living Cells30citations
  • 2022Developing Pd(ii) based amphiphilic polymeric nanoparticles for pro-drug activation in complex media21citations
  • 2022Spectrally PAINTing a Single Chain Polymeric Nanoparticle at Super-Resolution19citations
  • 2021Compartmentalized Polymers for Catalysis in Aqueous Media6citations
  • 2021Consequences of Chirality in Directing the Pathway of Cholesteric Helix Inversion of π-Conjugated Polymers by Light47citations
  • 2020Long-lived charge-transfer state from B−N frustrated Lewis pairs enchained in supramolecular copolymers124citations
  • 2020Tuning polymer properties of non-covalent crosslinked PDMS by varying supramolecular interaction strength28citations
  • 2019Detailed approach to investigate thermodynamically controlled supramolecular copolymerizations31citations
  • 2019Detailed approach to investigate thermodynamically controlled supramolecular copolymerizationscitations
  • 2019Stereocomplexes of discrete, isotactic lactic acid oligomers conjugated with oligodimethylsiloxanes41citations
  • 2019Future of supramolecular copolymers unveiled by reflecting on covalent copolymerization161citations
  • 2019Equilibrium model for supramolecular copolymerizations48citations
  • 2018Supramolecular block copolymers under thermodynamic control140citations
  • 2018Supramolecular block copolymers under thermodynamic controlcitations
  • 2017Self-assembly of hydrogen-bonding gradient copolymers28citations
  • 2017Self-assembly of hydrogen-bonding gradient copolymers:sequence control via tandem living radical polymerization with transesterification28citations
  • 2015The coil-to-globule transition of single-chain polymeric nanoparticles with a chiral internal secondary structure53citations
  • 2015Modular synthetic platform for the construction of functional single-chain polymeric nanoparticles:from aqueous catalysis to photosensitization132citations
  • 2015Modular synthetic platform for the construction of functional single-chain polymeric nanoparticles132citations
  • 2014Consequences of block sequence on the orthogonal folding of triblock copolymers21citations
  • 2014The effect of pendant benzene-1,3,5-tricarboxamides in the middle block of ABA triblock copolymers : synthesis and mechanical properties15citations
  • 2014Folding triblock copolymerscitations
  • 2014Folding polymers with pendant hydrogen bonding motifs in water : the effect of polymer length and concentration on the shape and size of single-chain polymeric nanoparticlescitations
  • 2014Folding polymers with pendant hydrogen bonding motifs in water : the effect of polymer length and concentration on the shape and size of single-chain polymeric nanoparticles92citations
  • 2013Sticky Supramolecular Grafts Stretch Single Polymer Chains76citations
  • 2013Orthogonal self-assembly in folding block copolymers192citations
  • 2012Benzene-1,3,5-tricarboxamide : a versatile ordering moiety for supramolecular chemistrycitations
  • 2012Benzene-1,3,5-tricarboxamide : a versatile ordering moiety for supramolecular chemistry390citations
  • 2010Hydrolases part I : enzyme mechanism, selectivity and control in the synthesis of well-defined polymers19citations
  • 2007Supramolecular copolyesters with tunable propertiescitations
  • 2007Supramolecular copolyesters with tunable properties59citations
  • 2007Poly(caprolactone-co-oxo-crown ether)-based poly(urethane)urea for soft tissue engineering applications17citations
  • 2006Oxo-crown-ethers as comonomers for tuning polyester propertiescitations
  • 2006Oxo-crown-ethers as comonomers for tuning polyester properties29citations

Places of action

Chart of shared publication
Sathyan, Anjana
2 / 3 shared
Unciti-Broceta, Asier
2 / 3 shared
Deng, Linlin
3 / 4 shared
Sebastián, Víctor
1 / 35 shared
Adam, Catherine
1 / 2 shared
Sijbesma, Rintje Pieter
2 / 5 shared
Majumdar, Soumabrata
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Tol, Joost J. B. Van Der
1 / 2 shared
Mallens, Jorg
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Sarkar, Ramkrishna
1 / 2 shared
Kuil, Sierd
1 / 2 shared
Heuts, Hans
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Albertazzi, Lorenzo
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Croke, Stephen
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Pérez-López, Ana M.
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Waal, Bas F. M. De
2 / 2 shared
Archontakis, Emmanouil
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Zijlstra, Peter
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Eisenreich, Fabian
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Curvers, Rick H. N.
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Broer, Dj Dirkdick
1 / 65 shared
Vantomme, Ghislaine
1 / 9 shared
Meskers, Stefan C. J.
2 / 29 shared
Meijer, Ew Bert
24 / 48 shared
Lamers, Brigitte A. G.
3 / 8 shared
Ogi, Soichiro
1 / 2 shared
Tanaka, Naoki
1 / 3 shared
Yamaguchi, Shigehiro
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Ślęczkowski, Marcin
1 / 1 shared
Wouters, Fabian
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Engels, Tom A. P.
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Windt, Lafayette N. J. De
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Markvoort, Albert
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Ten Eikelder, Huub
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Markvoort, Aj Bart
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Eikelder, Hmm Huub Ten
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Windt, Lnj Lafayette De
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Kulkarni, C.
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Van Genabeek, Bas
1 / 1 shared
Hennissen, J.
1 / 1 shared
Van Zee, Nathan
1 / 4 shared
Aloi, Antonio
1 / 2 shared
Voets, Ilja
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Adelizzi, B.
1 / 1 shared
Aloi, A. Antonio
1 / 1 shared
Voets, Ik Ilja
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Sawamoto, M.
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Artar, Müge
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Ogura, Y.
2 / 2 shared
Terashima, T.
2 / 4 shared
Artar, M. Muge
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Terashima, T. Takaya
1 / 1 shared
Gillissen, M. A. J.
5 / 8 shared
Huurne, G. M. Ter
1 / 1 shared
Pauloehrl, Tm Thomas
1 / 1 shared
Albertazzi, L. Lorenzo
1 / 1 shared
Liu, Y. Yiliu
1 / 1 shared
Presolski, Si Stanislav
1 / 1 shared
Liu, Y.
1 / 99 shared
Presolski, S. I.
1 / 1 shared
Pauloehrl, Th.
1 / 1 shared
Stals, Pjm Patrick
4 / 4 shared
Hosono, N. Nobuhiko
2 / 2 shared
Pitet, Louis
1 / 2 shared
Hosono, N.
2 / 2 shared
Lindner, Mm Menno
1 / 1 shared
Paffen, Tfe Tim
1 / 1 shared
Greef, Tfa Tom De
2 / 3 shared
Gillissen, Maj Martijn
2 / 3 shared
Paffen, T. F. E.
1 / 2 shared
De Greef, Tom
2 / 2 shared
Lindner, M. M.
1 / 2 shared
Sheiko, S. S.
1 / 1 shared
Li, Yuanchao
1 / 1 shared
Cantekin, S. Seda
1 / 1 shared
Cantekin, S.
1 / 2 shared
Veld, M. A. J.
1 / 1 shared
Beek, Djm Linda Van
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Sijbesma, Rp Rint
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As, Bac Bart Van
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Van, D. J. M. Beek
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Van, B. A. C. As
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Renken, R. A. E.
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Wisse, E.
1 / 1 shared
Roosma, J. R.
1 / 1 shared
Antens, Jbm Jany
1 / 1 shared
Kruijs, Bhp Bas Van De
1 / 1 shared
Mee, Lht Lars Van Der
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Van Der, L. H. T. Mee
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Van De, B. H. P. Kruijs
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Antens, J.
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Co-Authors (by relevance)

  • Sathyan, Anjana
  • Unciti-Broceta, Asier
  • Deng, Linlin
  • Sebastián, Víctor
  • Adam, Catherine
  • Sijbesma, Rintje Pieter
  • Majumdar, Soumabrata
  • Tol, Joost J. B. Van Der
  • Mallens, Jorg
  • Sarkar, Ramkrishna
  • Kuil, Sierd
  • Heuts, Hans
  • Albertazzi, Lorenzo
  • Croke, Stephen
  • Pérez-López, Ana M.
  • Waal, Bas F. M. De
  • Archontakis, Emmanouil
  • Zijlstra, Peter
  • Eisenreich, Fabian
  • Curvers, Rick H. N.
  • Broer, Dj Dirkdick
  • Vantomme, Ghislaine
  • Meskers, Stefan C. J.
  • Meijer, Ew Bert
  • Lamers, Brigitte A. G.
  • Ogi, Soichiro
  • Tanaka, Naoki
  • Yamaguchi, Shigehiro
  • Ślęczkowski, Marcin
  • Wouters, Fabian
  • Engels, Tom A. P.
  • Windt, Lafayette N. J. De
  • Markvoort, Albert
  • Ten Eikelder, Huub
  • Markvoort, Aj Bart
  • Eikelder, Hmm Huub Ten
  • Windt, Lnj Lafayette De
  • Kulkarni, C.
  • Van Genabeek, Bas
  • Hennissen, J.
  • Van Zee, Nathan
  • Aloi, Antonio
  • Voets, Ilja
  • Adelizzi, B.
  • Aloi, A. Antonio
  • Voets, Ik Ilja
  • Sawamoto, M.
  • Artar, Müge
  • Ogura, Y.
  • Terashima, T.
  • Artar, M. Muge
  • Terashima, T. Takaya
  • Gillissen, M. A. J.
  • Huurne, G. M. Ter
  • Pauloehrl, Tm Thomas
  • Albertazzi, L. Lorenzo
  • Liu, Y. Yiliu
  • Presolski, Si Stanislav
  • Liu, Y.
  • Presolski, S. I.
  • Pauloehrl, Th.
  • Stals, Pjm Patrick
  • Hosono, N. Nobuhiko
  • Pitet, Louis
  • Hosono, N.
  • Lindner, Mm Menno
  • Paffen, Tfe Tim
  • Greef, Tfa Tom De
  • Gillissen, Maj Martijn
  • Paffen, T. F. E.
  • De Greef, Tom
  • Lindner, M. M.
  • Sheiko, S. S.
  • Li, Yuanchao
  • Cantekin, S. Seda
  • Cantekin, S.
  • Veld, M. A. J.
  • Beek, Djm Linda Van
  • Sijbesma, Rp Rint
  • As, Bac Bart Van
  • Van, D. J. M. Beek
  • Van, B. A. C. As
  • Renken, R. A. E.
  • Wisse, E.
  • Roosma, J. R.
  • Antens, Jbm Jany
  • Kruijs, Bhp Bas Van De
  • Mee, Lht Lars Van Der
  • Van Der, L. H. T. Mee
  • Van De, B. H. P. Kruijs
  • Antens, J.
OrganizationsLocationPeople

article

Detailed approach to investigate thermodynamically controlled supramolecular copolymerizations

  • Palmans, Ara Anja
  • Windt, Lafayette N. J. De
  • Markvoort, Albert
  • Ten Eikelder, Huub
  • Meijer, Ew Bert
Abstract

<p>Elucidating the microstructure of supramolecular copolymers remains challenging, despite the progress in the field of supramolecular polymers. In this work, we present a detailed approach to investigate supramolecular copolymerizations under thermodynamic control. Our approach provides insight into the interactions of different types of monomers and hereby allows elucidating the microstructure of copolymers. We select two monomers that undergo cooperative supramolecular polymerization by way of threefold intermolecular hydrogen bonding in a helical manner, namely, benzene-1,3,5-tricarboxamide (BTA) and benzene-1,3,5-tris(carbothioamide) (thioBTA). Two enantiomeric forms and an achiral analogue of BTA and thioBTA are synthesized and their homo- and copolymerizations are studied using light scattering techniques, infrared, ultraviolet, and circular dichroism spectroscopy. After quantifying the thermodynamic parameters describing the homopolymerizations, we outline a method to follow the self-assembly of thioBTA derivatives in the copolymerization with BTA, which involves monitoring a characteristic spectroscopic signature as a function of temperature and relative concentration. Using modified types of sergeants-and-soldiers and majority-rules experiments, we obtain insights into the degree of aggregation and the net helicity. In addition, we apply a theoretical model of supramolecular copolymerization to substantiate the experimental results. We find that the model describes the two-component system well and allows deriving the hetero-interaction energies. The interactions between the same kinds of monomers (BTA-BTA and thioBTA-thioBTA) are slightly more favorable than those between different monomers (BTA-thioBTA), corresponding to a nearly random copolymerization. Finally, to study the interactions of the monomers at the molecular level, we perform density functional theory-based computations. The results corroborate that the two-component system exhibits a random distribution of the two monomer units along the copolymer chain.</p>

Topics
  • density
  • microstructure
  • theory
  • experiment
  • Hydrogen
  • density functional theory
  • random
  • copolymer
  • self-assembly
  • light scattering
  • circular dichroism spectroscopy