Materials Map

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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Naji, M.
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Palmans, Ara Anja

  • Google
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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (36/36 displayed)

  • 2024Enhanced Efficiency of Pd(0)-Based Single Chain Polymeric Nanoparticles for in Vitro Prodrug Activation by Modulating the Polymer’s Microstructure10citations
  • 2023Dynamic covalent networks with tunable dynamicity by mixing acylsemicarbazides and thioacylsemicarbazides8citations
  • 2022Elucidating the Stability of Single-Chain Polymeric Nanoparticles in Biological Media and Living Cells30citations
  • 2022Developing Pd(ii) based amphiphilic polymeric nanoparticles for pro-drug activation in complex media21citations
  • 2022Spectrally PAINTing a Single Chain Polymeric Nanoparticle at Super-Resolution19citations
  • 2021Compartmentalized Polymers for Catalysis in Aqueous Media6citations
  • 2021Consequences of Chirality in Directing the Pathway of Cholesteric Helix Inversion of π-Conjugated Polymers by Light47citations
  • 2020Long-lived charge-transfer state from B−N frustrated Lewis pairs enchained in supramolecular copolymers124citations
  • 2020Tuning polymer properties of non-covalent crosslinked PDMS by varying supramolecular interaction strength28citations
  • 2019Detailed approach to investigate thermodynamically controlled supramolecular copolymerizations31citations
  • 2019Detailed approach to investigate thermodynamically controlled supramolecular copolymerizationscitations
  • 2019Stereocomplexes of discrete, isotactic lactic acid oligomers conjugated with oligodimethylsiloxanes41citations
  • 2019Future of supramolecular copolymers unveiled by reflecting on covalent copolymerization161citations
  • 2019Equilibrium model for supramolecular copolymerizations48citations
  • 2018Supramolecular block copolymers under thermodynamic control140citations
  • 2018Supramolecular block copolymers under thermodynamic controlcitations
  • 2017Self-assembly of hydrogen-bonding gradient copolymers28citations
  • 2017Self-assembly of hydrogen-bonding gradient copolymers:sequence control via tandem living radical polymerization with transesterification28citations
  • 2015The coil-to-globule transition of single-chain polymeric nanoparticles with a chiral internal secondary structure53citations
  • 2015Modular synthetic platform for the construction of functional single-chain polymeric nanoparticles:from aqueous catalysis to photosensitization132citations
  • 2015Modular synthetic platform for the construction of functional single-chain polymeric nanoparticles132citations
  • 2014Consequences of block sequence on the orthogonal folding of triblock copolymers21citations
  • 2014The effect of pendant benzene-1,3,5-tricarboxamides in the middle block of ABA triblock copolymers : synthesis and mechanical properties15citations
  • 2014Folding triblock copolymerscitations
  • 2014Folding polymers with pendant hydrogen bonding motifs in water : the effect of polymer length and concentration on the shape and size of single-chain polymeric nanoparticlescitations
  • 2014Folding polymers with pendant hydrogen bonding motifs in water : the effect of polymer length and concentration on the shape and size of single-chain polymeric nanoparticles92citations
  • 2013Sticky Supramolecular Grafts Stretch Single Polymer Chains76citations
  • 2013Orthogonal self-assembly in folding block copolymers192citations
  • 2012Benzene-1,3,5-tricarboxamide : a versatile ordering moiety for supramolecular chemistrycitations
  • 2012Benzene-1,3,5-tricarboxamide : a versatile ordering moiety for supramolecular chemistry390citations
  • 2010Hydrolases part I : enzyme mechanism, selectivity and control in the synthesis of well-defined polymers19citations
  • 2007Supramolecular copolyesters with tunable propertiescitations
  • 2007Supramolecular copolyesters with tunable properties59citations
  • 2007Poly(caprolactone-co-oxo-crown ether)-based poly(urethane)urea for soft tissue engineering applications17citations
  • 2006Oxo-crown-ethers as comonomers for tuning polyester propertiescitations
  • 2006Oxo-crown-ethers as comonomers for tuning polyester properties29citations

Places of action

Chart of shared publication
Sathyan, Anjana
2 / 3 shared
Unciti-Broceta, Asier
2 / 3 shared
Deng, Linlin
3 / 4 shared
Sebastián, Víctor
1 / 35 shared
Adam, Catherine
1 / 2 shared
Sijbesma, Rintje Pieter
2 / 5 shared
Majumdar, Soumabrata
1 / 4 shared
Tol, Joost J. B. Van Der
1 / 2 shared
Mallens, Jorg
1 / 2 shared
Sarkar, Ramkrishna
1 / 2 shared
Kuil, Sierd
1 / 2 shared
Heuts, Hans
1 / 4 shared
Albertazzi, Lorenzo
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Croke, Stephen
1 / 2 shared
Pérez-López, Ana M.
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Waal, Bas F. M. De
2 / 2 shared
Archontakis, Emmanouil
1 / 1 shared
Zijlstra, Peter
1 / 1 shared
Eisenreich, Fabian
1 / 5 shared
Curvers, Rick H. N.
1 / 2 shared
Broer, Dj Dirkdick
1 / 65 shared
Vantomme, Ghislaine
1 / 9 shared
Meskers, Stefan C. J.
2 / 29 shared
Meijer, Ew Bert
24 / 48 shared
Lamers, Brigitte A. G.
3 / 8 shared
Ogi, Soichiro
1 / 2 shared
Tanaka, Naoki
1 / 3 shared
Yamaguchi, Shigehiro
1 / 2 shared
Ślęczkowski, Marcin
1 / 1 shared
Wouters, Fabian
1 / 2 shared
Engels, Tom A. P.
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Windt, Lafayette N. J. De
2 / 2 shared
Markvoort, Albert
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Ten Eikelder, Huub
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Markvoort, Aj Bart
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Eikelder, Hmm Huub Ten
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Windt, Lnj Lafayette De
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Kulkarni, C.
1 / 3 shared
Van Genabeek, Bas
1 / 1 shared
Hennissen, J.
1 / 1 shared
Van Zee, Nathan
1 / 4 shared
Aloi, Antonio
1 / 2 shared
Voets, Ilja
4 / 9 shared
Adelizzi, B.
1 / 1 shared
Aloi, A. Antonio
1 / 1 shared
Voets, Ik Ilja
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Sawamoto, M.
2 / 2 shared
Artar, Müge
1 / 1 shared
Ogura, Y.
2 / 2 shared
Terashima, T.
2 / 4 shared
Artar, M. Muge
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Terashima, T. Takaya
1 / 1 shared
Gillissen, M. A. J.
5 / 8 shared
Huurne, G. M. Ter
1 / 1 shared
Pauloehrl, Tm Thomas
1 / 1 shared
Albertazzi, L. Lorenzo
1 / 1 shared
Liu, Y. Yiliu
1 / 1 shared
Presolski, Si Stanislav
1 / 1 shared
Liu, Y.
1 / 99 shared
Presolski, S. I.
1 / 1 shared
Pauloehrl, Th.
1 / 1 shared
Stals, Pjm Patrick
4 / 4 shared
Hosono, N. Nobuhiko
2 / 2 shared
Pitet, Louis
1 / 2 shared
Hosono, N.
2 / 2 shared
Lindner, Mm Menno
1 / 1 shared
Paffen, Tfe Tim
1 / 1 shared
Greef, Tfa Tom De
2 / 3 shared
Gillissen, Maj Martijn
2 / 3 shared
Paffen, T. F. E.
1 / 2 shared
De Greef, Tom
2 / 2 shared
Lindner, M. M.
1 / 2 shared
Sheiko, S. S.
1 / 1 shared
Li, Yuanchao
1 / 1 shared
Cantekin, S. Seda
1 / 1 shared
Cantekin, S.
1 / 2 shared
Veld, M. A. J.
1 / 1 shared
Beek, Djm Linda Van
1 / 2 shared
Sijbesma, Rp Rint
1 / 5 shared
As, Bac Bart Van
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Van, D. J. M. Beek
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Van, B. A. C. As
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Renken, R. A. E.
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Wisse, E.
1 / 1 shared
Roosma, J. R.
1 / 1 shared
Antens, Jbm Jany
1 / 1 shared
Kruijs, Bhp Bas Van De
1 / 1 shared
Mee, Lht Lars Van Der
1 / 1 shared
Van Der, L. H. T. Mee
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Van De, B. H. P. Kruijs
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Antens, J.
1 / 2 shared
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Co-Authors (by relevance)

  • Sathyan, Anjana
  • Unciti-Broceta, Asier
  • Deng, Linlin
  • Sebastián, Víctor
  • Adam, Catherine
  • Sijbesma, Rintje Pieter
  • Majumdar, Soumabrata
  • Tol, Joost J. B. Van Der
  • Mallens, Jorg
  • Sarkar, Ramkrishna
  • Kuil, Sierd
  • Heuts, Hans
  • Albertazzi, Lorenzo
  • Croke, Stephen
  • Pérez-López, Ana M.
  • Waal, Bas F. M. De
  • Archontakis, Emmanouil
  • Zijlstra, Peter
  • Eisenreich, Fabian
  • Curvers, Rick H. N.
  • Broer, Dj Dirkdick
  • Vantomme, Ghislaine
  • Meskers, Stefan C. J.
  • Meijer, Ew Bert
  • Lamers, Brigitte A. G.
  • Ogi, Soichiro
  • Tanaka, Naoki
  • Yamaguchi, Shigehiro
  • Ślęczkowski, Marcin
  • Wouters, Fabian
  • Engels, Tom A. P.
  • Windt, Lafayette N. J. De
  • Markvoort, Albert
  • Ten Eikelder, Huub
  • Markvoort, Aj Bart
  • Eikelder, Hmm Huub Ten
  • Windt, Lnj Lafayette De
  • Kulkarni, C.
  • Van Genabeek, Bas
  • Hennissen, J.
  • Van Zee, Nathan
  • Aloi, Antonio
  • Voets, Ilja
  • Adelizzi, B.
  • Aloi, A. Antonio
  • Voets, Ik Ilja
  • Sawamoto, M.
  • Artar, Müge
  • Ogura, Y.
  • Terashima, T.
  • Artar, M. Muge
  • Terashima, T. Takaya
  • Gillissen, M. A. J.
  • Huurne, G. M. Ter
  • Pauloehrl, Tm Thomas
  • Albertazzi, L. Lorenzo
  • Liu, Y. Yiliu
  • Presolski, Si Stanislav
  • Liu, Y.
  • Presolski, S. I.
  • Pauloehrl, Th.
  • Stals, Pjm Patrick
  • Hosono, N. Nobuhiko
  • Pitet, Louis
  • Hosono, N.
  • Lindner, Mm Menno
  • Paffen, Tfe Tim
  • Greef, Tfa Tom De
  • Gillissen, Maj Martijn
  • Paffen, T. F. E.
  • De Greef, Tom
  • Lindner, M. M.
  • Sheiko, S. S.
  • Li, Yuanchao
  • Cantekin, S. Seda
  • Cantekin, S.
  • Veld, M. A. J.
  • Beek, Djm Linda Van
  • Sijbesma, Rp Rint
  • As, Bac Bart Van
  • Van, D. J. M. Beek
  • Van, B. A. C. As
  • Renken, R. A. E.
  • Wisse, E.
  • Roosma, J. R.
  • Antens, Jbm Jany
  • Kruijs, Bhp Bas Van De
  • Mee, Lht Lars Van Der
  • Van Der, L. H. T. Mee
  • Van De, B. H. P. Kruijs
  • Antens, J.
OrganizationsLocationPeople

article

Stereocomplexes of discrete, isotactic lactic acid oligomers conjugated with oligodimethylsiloxanes

  • Palmans, Ara Anja
  • Lamers, Brigitte A. G.
  • Van Genabeek, Bas
  • Hennissen, J.
  • Meijer, Ew Bert
  • Waal, Bas F. M. De
Abstract

<p>Discrete length block co-oligomers (BCOs) comprised of a crystalline and an amorphous block are a new class of materials that gives highly ordered lamellar morphologies at small length scales. Here, we show the preparation of discrete, isotactic oligo l- and d-lactic acid (olLA and odLA) homoblocks followed by ligation to oligodimethylsiloxane (oDMS), affording a library of crystalline-amorphous BCOs that vary in molecular weight and composition. Mixing the two enantiomeric BCOs or homoblocks results in the formation of the corresponding stereocomplex. The properties and phase behavior of the isotactic (block co)oligomers and the stereocomplexes thereof are studied using differential scanning calorimetry and small-angle X-ray scattering. A systematic study of the isotactic homoblock lengths and crystal structure confirmed the formation of a 10<sub>3</sub>helix with a monomeric rise of 0.3 nm, whereas the stereocomplex adopts a 3<sub>1</sub>helix. The same type of crystal structure was found for the isotactic and stereocomplex of BCOs giving rise to the formation of lamellar morphologies at room temperature as a result of crystallization of the oLA blocks. Distorted lamellar structures were found in BCOs that preorganize into nonlamellar morphologies prior to crystallization. The stereocomplex BCOs shows more crystal defects and a loss of long-range ordering in the microstructure due to the larger driving force for crystallization. Hence, the balance between chain length, block volume, and the crystallization strength are of major importance for the formation of the final structure with the least defects.</p>

Topics
  • amorphous
  • phase
  • strength
  • defect
  • differential scanning calorimetry
  • molecular weight
  • crystallization
  • X-ray scattering
  • lamellae