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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Koynov, Kaloian
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Topics
Publications (10/10 displayed)
- 2024Pressure Changes Across a Membrane Formed by Coacervation of Oppositely Charged Polymer-Surfactant Systemscitations
- 2023Complex Structures Made Simple – Continuous Flow Production of Core Cross-Linked Polymeric Micelles for Paclitaxel Pro-Drug-Delivery ; ENEngelskEnglishComplex Structures Made Simple – Continuous Flow Production of Core Cross-Linked Polymeric Micelles for Paclitaxel Pro-Drug-Deliverycitations
- 2023Complex Structures Made Simple - Continuous Flow Production of Core Cross-Linked Polymeric Micelles for Paclitaxel Pro-Drug-Deliverycitations
- 2022Plasma polymer barrier layers to control the release kinetics from dissolvable microneedle patchescitations
- 2022Temperature Controlled Mechanical Reinforcement of Polyacrylate Films Containing Nematic Liquid Crystalscitations
- 2021Macroscopic Viscosity of Polymer Solutions from the Nanoscale Analysiscitations
- 2019Nanotopography-Induced Unfolding of Fibrinogen Modulates Leukocyte Binding and Activationcitations
- 2018FRET monitoring of intracellular ketal hydrolysis in synthetic nanoparticlescitations
- 2017Dynamic Heterogeneity in Random Copolymers of Polymethacrylates Bearing Different Polyhedral Oligomeric Silsesquioxane Moieties (POSS)citations
- 2015Polymethacrylates with polyhedral oligomeric silsesquioxane (POSS) moieties: Influence of spacer length on packing, thermodynamics, and dynamicscitations
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article
Polymethacrylates with polyhedral oligomeric silsesquioxane (POSS) moieties: Influence of spacer length on packing, thermodynamics, and dynamics
Abstract
<p>Polymethacrylates with polyhedral oligomeric silsesquioxane (POSS) moieties (poly(POSS-MA)s) with flexible spacers between the POSS cages and the methacrylate group have distinctly different properties from their linear counterpart, i.e., PMMA. POSS cages modify interchain correlations and result in multiple dynamic processes that reflect the cooperative relaxations of both the pendant POSS units and ester dipoles and the polymer backbone. As a result, the freezing of the backbone dynamics is shifted to lower temperatures, and the nanocomposites appear softer than linear PMMA chains of similar degrees of polymerization. POSS cages can be employed as nanometer size blocks that, depending on the polymer backbone and the spacer, can impart mobility and control over the mechanical properties of nanocomposites.</p>