| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Boyer, Cyrille
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Microphase Separation 3D Printing of Binary Inorganic Polymer Precursors to Prepare Nanostructured Carbon‐Ceramic Multimaterialscitations
- 2024Design and 3D Printing of Polyacrylonitrile‐Derived Nanostructured Carbon Architecturescitations
- 2023Microphase Separation 3D Printing of Binary Inorganic Polymer Precursors to Prepare Nanostructured Carbon‐Ceramic Multimaterialscitations
- 2023Exploiting NIR light mediated Surface-Initiated PhotoRAFT polymerization for orthogonal control polymer brushes and facile post-modification of complex architecture through opaque barrierscitations
- 2022Soft Liquid Metal Infused Conductive Spongescitations
- 2022P003 Synthetic antifungal peptide mimic kills <i>Candida albicans</i> by targeting protein glycosylation and synergistically prevents infection
- 2021Incorporation and antimicrobial activity of nisin Z within carrageenan/chitosan multilayerscitations
- 2018Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertioncitations
- 2011High-order multiblock copolymers via iterative Cu(0)-mediated radical polymerizations (SET-LRP): Toward biological precisioncitations
- 2010Telechelic Diiodopoly(VDF-co-PMVE) Copolymers by Iodine Transfer Copolymerization of Vinylidene Fluoride (VDF) with Perfluoromethyl vinyl ether (PMVE)citations
- 2010Synthesis of hollow polymer nanocapsules exploiting gold nanoparticles as sacrificial templatescitations
- 2009Iodine Transfer Copolymerization of Vinylidene Fluoride and a-Trifluoromethacrylic Acid in Emulsion Process Without Any Surfactantscitations
- 2008Radical Terpolymerization of 1,1,2-Trifluoro-2-pentafluorosulfanylethylene and Pentafluorosulfanylethylene in the Presence of Vinylidene Fluoride and Hexafluoropropylene by Iodine Transfer Polymerizationcitations
- 2008Synthesis of triblock copolymers from glycolysed poly(ethylene terephthalate) by living radical polymerizationcitations
- 2007Synthesis and Characterisation of Organogels from ABA Triblock Copolymerscitations
- 2007Synthesis and Characterisation of Organogels from ABA Triblock Copolymerscitations
- 2006Kinetics of the iodine transfer polymerization of vinylidene fluoridecitations
- 2006Reverse Iodine Transfer Polymerization (RITP) of Methyl Methacrylatecitations
- 2006Poly(vinylidene fluoride)-b-poly(styrene) Block Copolymers by Iodine Transfer Polymerization (ITP): Synthesis, Characterization, and Kinetics of ITPcitations
- 2005Iodine Transfer Polymerization (ITP) of Vinylidene Fluoride (VDF). Influence of the Defect of VDF Chaining on the Control of ITPcitations
Places of action
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article
Exploiting NIR light mediated Surface-Initiated PhotoRAFT polymerization for orthogonal control polymer brushes and facile post-modification of complex architecture through opaque barriers
Abstract
An oxygen-tolerant SI-PhotoRAFT technique has been developed for the efficient synthesis of surface-tethered polymer brushes under low-energy near-infrared (NIR) light. This technique takes advantage of the unique properties of NIR light, in particular enhanced penetration, to effectively prepare polymeric coatings even through opaque barriers. The NIR-mediated SI-PhotoRAFT polymerization exhibits polymerization kinetics characteristic of reversible deactivation radical polymerization (RDRP), a linear increase in brush height with irradiation time, and sequential chain extension to form block copolymer brushes. Moreover, the incorporation of a photoresponsive monomer, 7-[4-(trifluoromethyl)coumarin] acrylamide (TCAm), within the poly(dimethylacrylamide) brushes enables orthogonal control over polymerization and crosslinking processes using two different wavelengths (NIR and UV light). When exposed to a UV source (λ = 365 nm, 18.2 mW/cm2), the TCAm undergoes dimerization triggering crosslinking of the grafted brush ‘arms’. Furthermore, by utilizing the enhanced penetration of NIR light, a polymeric coating was prepared on the inner walls of opaque tube. Finally, this process is successfully applied to the synthesis of antifouling surfaces on poly(dimethyl siloxane) (PDMS) coated silicon wafers leading to inhibition of biofouling.