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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pich, Andrij
Maastricht University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Enhancing Adhesion of Fibrin-Based Hydrogel to Polythioether Polymer Surfacescitations
- 2023Novel Pectin Binder for Satelliting Carbides to H13 Tool Steel for PBF-LB Processingcitations
- 2022Characterization of transient rheological behavior of soft materials using ferrofluid dropletscitations
- 2022Generation of local diffusioosmotic flow by light responsive microgelscitations
- 2021Post-Modification of Biobased Pyrazines and Their Polyesterscitations
- 2020Stimuli-Responsive Zwitterionic Core-Shell Microgels for Antifouling Surface Coatingscitations
- 2020Amphiphilic PVCL/TBCHA microgelscitations
- 2020Ranking of fiber composites by estimation of types and mechanisms of their fracturecitations
- 2020Polyphosphazene-Tannic Acid Colloids as Building Blocks for Bio-Based Flame-Retardant Coatingscitations
- 2020Mononuclear zinc(II) Schiff base complexes as catalysts for the ring-opening polymerization of lactidecitations
- 2020Dual-Temperature-Responsive Microgels from a Zwitterionic Functional Graft Copolymer with Superior Protein Repelling Propertycitations
- 2019Heterolepic β ‐Ketoiminate Zinc Phenoxide Complexes as Efficient Catalysts for the Ring Opening Polymerization of Lactidecitations
- 2019Selenium-Modified Microgels as Bio-Inspired Oxidation Catalystscitations
- 2019Heterolepic β-Ketoiminate Zinc Phenoxide Complexes as Efficient Catalysts for the Ring Opening Polymerization of Lactidecitations
- 2019Heterolepic β‐Ketoiminate Zinc Phenoxide Complexes as Efficient Catalysts for the Ring Opening Polymerization of Lactide
- 2019Tuning Channel Architecture of Interdigitated Organic Electrochemical Transistors for Recording the Action Potentials of Electrogenic Cellscitations
- 2017Internal structure and phase transition behavior of stimuli-responsive microgels in PEG meltscitations
- 2014Water dispersible electrically conductive poly(3,4- ethylenedioxythiophene) nanospindles by liquid crystalline template assisted polymerizationcitations
- 2013Formation of catalytically active gold-polymer microgel hybrids via a controlled in situ reductive processcitations
Places of action
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article
Post-Modification of Biobased Pyrazines and Their Polyesters
Abstract
Monomers and polymers from biobased pyrazine underwent post-modification reactions to synthesize a series of novel tailored polyesters with a tunable structure and adjustable physico-chemical properties. Modification by alkylation had limited success. However, controlled oxidative post-modification is possible, without loss of molecular weight. The degree of oxidation has a large effect on the thermal properties of the polyesters. One of the polyesters shows loss of crystallinity combined with an increase in the glass-transition temperature at increasing degrees of oxidation. For the other polyester, oxidation results in an elevated melting point. Weak hydrogen bonds are responsible for the latter observation as demonstrated by infrared spectroscopy. The surface modification of a polymer film results in different wetting behaviors. Our biobased pyrazine building blocks and their ability to be post-modified offer interesting opportunities in added functionality materials of the future.