| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Reineke, Theresa M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Mechanical Recycling of 3D-Printed Thermosets for Reuse in Vat Photopolymerizationcitations
- 2023Radical ring-opening polymerization of sustainably-derived thionoisochromanonecitations
- 2023Biobased Copolymers via Cationic Ring-Opening Copolymerization of Levoglucosan Derivatives and ϵ-Caprolactonecitations
- 2023Biobased and degradable thiol-ene networks from levoglucosan for sustainable 3D printingcitations
- 2021Degradable polyanhydride networks derived from itaconic acidcitations
- 2021Structural Basis for the Different Mechanical Behaviors of Two Chemically Analogous, Carbohydrate-Derived Thermosetscitations
- 2021Sustainable advances in SLA/DLP 3D printing materials and processescitations
- 2021Regioregular Polymers from Biobased (R)-1,3-Butylene Carbonatecitations
- 2019Properties of Chemically Cross-Linked Methylcellulose Gelscitations
- 2018Isothermal Titration Calorimetry for the Screening of Aflatoxin B1 Surface-Enhanced Raman Scattering Sensor Affinity Agentscitations
- 2016Acrylic Triblock Copolymers Incorporating Isosorbide for Pressure Sensitive Adhesivescitations
- 2015Isosorbide-based polymethacrylatescitations
- 2014Degradable thermosets from sugar-derived dilactonescitations
- 2012Glucose-functionalized, serum-stable polymeric micelles from the combination of anionic and RAFT polymerizationscitations
Places of action
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article
Regioregular Polymers from Biobased (R)-1,3-Butylene Carbonate
Abstract
<p>We present (R)-1,3-butylene carbonate (R-BC) as a biorenewable monomer for the preparation of semicrystalline aliphatic polycarbonates. This conversion is achieved by using enantiomerically pure, biobased (R)-(-)-1,3-butanediol (bio-BG) as a renewable feedstock. Ring-opening polymerization from select catalysts at low temperatures can yield regioregular poly((R)-1,3-butylene carbonate) (R-PBC) with semicrystalline properties (Xreg = > 0.99; Tm = 72 °C). Along with the R-enantiomeric polymer, the alternate stereochemical polymers (using S- and racemic BC) were investigated. Our analysis shows that the highest level of crystallinity is achieved with regioregular, biobased R-PBC compared to the petrol-based S- and racemic congeners. This work shows the potential of stereochemically pure bio-BG as a starting material for semicrystalline, aliphatic carbonates when high regioregularity is achieved in the polymer microstructure. The synthesis and thermal characterization of regioregular butylene carbonate polymers are described in detail.</p>