Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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Materials Map under construction

The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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Portale, Giuseppe, A.

  • Google
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University of Groningen

in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (57/57 displayed)

  • 2024Quasi-2D Lead–Tin Perovskite Memory Devices Fabricated by Blade Coating10citations
  • 2024PbI2 Passivation of Three Dimensional PbS Quantum Dot Superlattices Toward Optoelectronic Metamaterials3citations
  • 2023Effect of Dynamically Arrested Domains on the Phase Behavior, Linear Viscoelasticity and Microstructure of Hyaluronic Acid - Chitosan Complex Coacervates13citations
  • 2023Tuning the energy transfer in Ruddlesden-Popper perovskites phases through isopropylammonium addition - towards efficient blue emitters5citations
  • 2023Nickel Boride (NixB) Nanocrystals14citations
  • 2023The human factor3citations
  • 2023Addition of Ammonium Thiocyanate Alters the Microstructure and Energetic Landscape of 2D/3D Perovskite Filmscitations
  • 2022Film formation mechanism uncovered in 2D/3D mixed-dimensional lead halide perovskites1citations
  • 2022Confined crystallization and polymorphism in iPP thin films4citations
  • 2022Two-Dimensional Triblock Peptide Assemblies for the Stabilization of Pickering Emulsions with pH Responsiveness4citations
  • 2022Nanoscale Networks of Metal Oxides by Polymer Imprinting and Templating for Future Adaptable Electronics1citations
  • 2022Crystallization kinetics of melt-mixed 3D hierarchical graphene/ polypropylene nanocomposites at processing-relevant cooling rates6citations
  • 2022Taking a closer look - how the microstructure of Dion-Jacobson perovskites governs their photophysicscitations
  • 2022Taking a closer look - how the microstructure of Dion-Jacobson perovskites governs their photophysics1citations
  • 2021Structural Transitions During Formation and Rehydration of Proton Conducting Polymeric Membranes1citations
  • 2021Amphipathic Side Chain of a Conjugated Polymer Optimizes Dopant Location toward Efficient N-Type Organic Thermoelectrics123citations
  • 2021Data Mining of Polymer Phase Transitions upon Temperature Changes by Small and Wide-Angle X-ray Scattering Combined with Raman Spectroscopy4citations
  • 2021Boosting the Thermoelectric Properties of PEDOT20citations
  • 2021Crystallization driven boost in fill factor and stability in additive-free organic solar cells18citations
  • 2021Molecular Doping Directed by a Neutral Radical14citations
  • 2021Proton conducting ABA triblock copolymers with sulfonated poly(phenylene sulfide sulfone) midblock obtained via copper-free thiol-click chemistry dagger4citations
  • 2021Revisiting the Mechanism of the Meso-to-α Transition of Isotactic Polypropylene and Ethylene-Propylene Random Copolymers7citations
  • 2021Scalable, Template Driven Formation of Highly Crystalline Lead-Tin Halide Perovskite Films27citations
  • 2020Rapid Self-Assembly and Sequential Infiltration Synthesis of High χ Fluorine-Containing Block Copolymers15citations
  • 2020Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chains8citations
  • 2020Electrical Conductivity of Doped Organic Semiconductors Limited by Carrier-Carrier Interactions55citations
  • 2020Systematic Investigation on the Structure-Property Relationship in Isotactic Polypropylene Films Processed via Cast Film Extrusion14citations
  • 2020Unraveling the Microstructure of Layered Metal Halide Perovskite Films9citations
  • 2020N-type organic thermoelectrics153citations
  • 2020Highly Stable Membranes of Poly(phenylene sulfide benzimidazole) Cross-Linked with Polyhedral Oligomeric Silsesquioxanes for High-Temperature Proton Transport26citations
  • 2019Stable Cesium Formamidinium Lead Halide Perovskites24citations
  • 2019Enhancing the crystallinity and perfecting the orientation of formamidinium tin iodide for highly efficient Sn-based perovskite solar cells160citations
  • 2019Improved energy density and charge-discharge efficiency in solution processed highly defined ferroelectric block copolymer-based dielectric nanocomposites19citations
  • 2019Supramolecular Mimic for Bottlebrush Polymers in Bulk15citations
  • 2019Favorable Mixing Thermodynamics in Ternary Polymer Blends for Realizing High Efficiency Plastic Solar Cells47citations
  • 2019Chemical Solution Deposition of Ordered 2D Arrays of Room-Temperature Ferrimagnetic Cobalt Ferrite Nanodots8citations
  • 2019A Photoaddressable Liquid Crystalline Phase Transition in Graphene Oxide Nanocomposites3citations
  • 2019Investigation of the Nanoscale Morphology in Industrially Relevant Clearcoats of Waterborne Polymer Colloids by Means of Variable-Angle-Grazing Incidence Small-Angle X-ray Scattering8citations
  • 2019Monitoring morphology evolution within block copolymer microparticles during dispersion polymerisation in supercritical carbon dioxide21citations
  • 2018Operando SAXS/WAXS on the a-P/C as the Anode for Na-Ion Batteries14citations
  • 2017Templated Sub-100-nm-Thick Double-Gyroid Structure from Si-Containing Block Copolymer Thin Films18citations
  • 2017On the Dimensional Control of 2D Hybrid Nanomaterials4citations
  • 2017Sub-micrometer structure formation during spin coating revealed by time-resolved in situ laser and X-ray scattering38citations
  • 2017N-Type Organic Thermoelectrics153citations
  • 2016Structurally-driven Enhancement of Thermoelectric Properties within Poly(3,4-ethylenedioxythiophene) thin Films82citations
  • 2016Bundle Formation in Biomimetic Hydrogels53citations
  • 2016Improving Stiffness, Strength, and Toughness of Poly(omega-pentadecalactone) Fibers through in Situ Reinforcement with a Vanillic Acid-Based Thermotropic Liquid Crystalline Polyester21citations
  • 2016Tuning Ordered Pattern of Pd Species through Controlled Block Copolymer Self-Assembly7citations
  • 2015About the Interactions Controlling Nafion's Viscoelastic Properties and Morphology24citations
  • 2015Polymer Solar Cells145citations
  • 2015In situ monitoring of laser-induced periodic surface structures formation on polymer films by grazing incidence small-angle X-ray scattering28citations
  • 2015Photoresponsive Nanoporous Smectic Liquid Crystalline Polymer Networks31citations
  • 2015Unusual Melting Behavior in Flow Induced Crystallization of LLDPE22citations
  • 2014Influence of metal-support interaction on the surface structure of gold nanoclusters deposited on native SiO(x)/Si substrates25citations
  • 2014Kinetics of the polymorphic transition in isotactic poly(1-butene) under uniaxial extension. New insights from designed mechanical histories78citations
  • 2014A high pressure cell for supercritical CO2 on-line chemical reactions studied with x-ray techniques19citations
  • 2007Small-angle energy-dispersive X-ray scattering using a laboratory-based diffractometer with a conventional source6citations

Places of action

Chart of shared publication
Tekelenburg, Eelco K.
1 / 14 shared
Chen, Lijun
1 / 4 shared
Loi, Maria Antonietta
13 / 73 shared
Tran, Karolina
1 / 4 shared
Brabec, Cj
2 / 407 shared
Kooi, Bart Jan
4 / 74 shared
Carlà, Francesco
1 / 13 shared
Pinna, Jacopo
1 / 2 shared
Pili, Elisa
1 / 1 shared
Gavhane, Dnyaneshwar S.
1 / 1 shared
Koushki, Razieh Mehrabi
1 / 1 shared
Amirsadeghi, Armin
1 / 2 shared
Dittberner, Olivia
1 / 2 shared
Parisi, Daniele
1 / 24 shared
Yunus, Roshan Akdar Mohamed
1 / 1 shared
Van Westerveld, Larissa
1 / 4 shared
Caïto, Clément
1 / 2 shared
Calicchia, Eleonora
2 / 3 shared
Maret, Denise
1 / 2 shared
Arunachalam, Abinaya
1 / 3 shared
Kamperman, Marleen
1 / 26 shared
Sayed, Julien Es
1 / 4 shared
Mario, Lorenzo Di
2 / 4 shared
Mura, Andrea
1 / 26 shared
Huitrón, Juan Carlos Alonso
1 / 1 shared
Bongiovanni, Giovanni
1 / 23 shared
Kahmann, Simon
5 / 30 shared
Rivera-Medina, Martha J.
1 / 3 shared
Hong, Jennifer
1 / 3 shared
Mutalik, Suhas
1 / 5 shared
Protesescu, Loredana
1 / 26 shared
Gerlach, Dominic
2 / 6 shared
Rudolf, Petra
3 / 62 shared
Pescarmona, Paolo P.
1 / 16 shared
Razieh Mehrabi, K.
1 / 1 shared
Ahmadi, Majid
1 / 28 shared
Miola, Matteo
1 / 10 shared
Shao, Shuyan
2 / 6 shared
Duim, Herman
6 / 25 shared
Rommens, Alex J.
1 / 1 shared
Jong, Leon De
1 / 1 shared
Pelras, Théophile
1 / 2 shared
Sacco, Federico Di
4 / 5 shared
Jurewicz, Izabela
1 / 4 shared
Keddie, Joseph L.
1 / 10 shared
Munoz, Edgar
1 / 3 shared
Howlin, Brendan J.
1 / 24 shared
Huang, Zhiwei
1 / 1 shared
Garriga, Rosa
1 / 6 shared
Berg, Alexandra I.
1 / 3 shared
Jonkman, Harry
1 / 1 shared
Loos, Katja U.
7 / 56 shared
Noheda, Beatriz
2 / 41 shared
Tranchida, Davide
1 / 6 shared
Kadar, Roland
1 / 3 shared
Carmeli, Enrico
1 / 8 shared
Cavallo, Dario
2 / 44 shared
Gkourmpis, Thomas
1 / 3 shared
Gitsas, Antonis
1 / 3 shared
Frohna, Kyle
2 / 35 shared
Duim, H.
1 / 1 shared
Rommens, Aj
1 / 1 shared
Ten Brink, Gert H.
7 / 32 shared
Rommens, Alexander J.
1 / 2 shared
Stranks, Samuel D.
1 / 101 shared
Viviani, Marco
3 / 7 shared
Lova, Paola
1 / 10 shared
Baran, Derya
3 / 11 shared
Villalva, Diego Rosas
1 / 2 shared
Havenith, Remco W. A.
2 / 22 shared
Dong, Jingjin
8 / 15 shared
Qiu, Xinkai
2 / 9 shared
Nugraha, Mohamad Insan
1 / 6 shared
Koster, Lja
5 / 32 shared
Sun, Hengda
1 / 8 shared
Koopmans, Marten
3 / 8 shared
Yao, Chen
1 / 2 shared
Yang, Xuwen
1 / 2 shared
Anthopoulos, Thomas D.
2 / 33 shared
Potgieser, Hinderikus G. O.
1 / 2 shared
Liu, Jian
5 / 26 shared
Ye, Gang
2 / 6 shared
Fabiano, Simone
1 / 34 shared
Bras, Wim
4 / 15 shared
Chapron, David
1 / 10 shared
Saidi, Sarah
2 / 4 shared
Amigo, José Manuel
1 / 1 shared
Hermida-Merino, Daniel
8 / 24 shared
Longo, Alessandro
5 / 20 shared
Bourson, Patrice
1 / 14 shared
Koutsogiannis, Panagiotis
1 / 6 shared
Garcia Romero, David
1 / 5 shared
Kamperman, Max
1 / 2 shared
Zee, Bas Van Der
2 / 2 shared
Villava, Diego R.
1 / 2 shared
Hummelen, Jan
4 / 10 shared
Fluitman, Sebastiaan Pieter
2 / 2 shared
Pitaro, Matteo
1 / 13 shared
Gahlot, Kushagra
1 / 8 shared
Hadziioannou, Georges
3 / 42 shared
Shi, Yulin
1 / 1 shared
Pino, Guillaume
1 / 1 shared
Demazy, Nils
1 / 2 shared
Fleury, Guillaume
3 / 25 shared
Mantione, Daniele
1 / 14 shared
Cummins, Cian
1 / 5 shared
Cruciani, Federico
1 / 3 shared
Mulder, Pascal
1 / 1 shared
Faraji, Shirin
2 / 7 shared
Maniar, Dina
2 / 10 shared
Golkaram, Milad
2 / 7 shared
Leiviskä, Miina A. T.
1 / 2 shared
Heiber, Michael C.
1 / 2 shared
Gahleitner, Markus
1 / 6 shared
Wang, Jingbo
1 / 7 shared
Adjokatse, Sampson
2 / 21 shared
Kloe, René De
1 / 2 shared
Rousseva, Sylvia
1 / 7 shared
Marrink, Siewert
1 / 3 shared
Nugraha, Mohamad I.
1 / 3 shared
Klasen, Nathalie
1 / 2 shared
Caironi, Mario
1 / 15 shared
Barker, Alex J.
1 / 7 shared
Blake, Graeme R.
2 / 46 shared
Groeneveld, Bart
1 / 1 shared
Nazarenko, Olga
1 / 15 shared
Kovalenko, Maksym
1 / 8 shared
Meereboer, Niels L.
1 / 4 shared
Terzic, Ivan
1 / 2 shared
Ruymbeke, Evelyne Van
1 / 3 shared
Fodor, Csaba
1 / 8 shared
Boetje, Laura
1 / 6 shared
Suarez, Luis Enrique Aguilar
1 / 2 shared
Li, Ning
1 / 16 shared
Spiecker, Erdmann
1 / 70 shared
Ameri, Tayebeh
1 / 18 shared
Perea, Jose Dario
1 / 1 shared
Sperlich, Andreas
1 / 3 shared
Salvador, Michael
1 / 4 shared
Dyakonov, Vladimir
1 / 20 shared
Gasparini, Nicola
1 / 20 shared
Rechberger, Stefanie
1 / 5 shared
Baumann, Andreas
1 / 8 shared
Syariati, Ali
1 / 3 shared
Heuver, Jeroen A.
1 / 1 shared
Momand, Jamo
1 / 22 shared
Varghese, Justin
1 / 1 shared
Xu, Jin
1 / 3 shared
Picot, Olivier
1 / 2 shared
Gautrot, Julien E.
1 / 5 shared
Crespo, Maria
1 / 3 shared
Santagiuliana, Giovanni
1 / 3 shared
Bilotti, Emiliano
1 / 34 shared
Scheerder, Jurgen
1 / 1 shared
Vagias, Apostolos
1 / 6 shared
Chen, Qi
1 / 5 shared
Howdle, Steven M.
2 / 16 shared
Bassett, Simon P.
2 / 3 shared
Bennett, Thomas M.
1 / 2 shared
He, Guping
1 / 1 shared
Alauhdin, Mohammad
1 / 2 shared
Knudsen, Kenneth Dahl
1 / 6 shared
Povia, Mauro
1 / 2 shared
Margadonna, Serena
1 / 7 shared
Sartori, Sabrina
1 / 17 shared
Sottmann, Jonas
1 / 3 shared
Cloutet, Eric
1 / 34 shared
Mumtaz, Muhammad
1 / 10 shared
Aissou, Karim
1 / 11 shared
Brochon, Cyril
1 / 17 shared
Kuringen, Huub P. C. Van
2 / 2 shared
Spoelstra, Anne B.
2 / 6 shared
Banerjee, Dipanjan
1 / 14 shared
Broer, Dirk J.
2 / 11 shared
Shishmanova, Irina K.
1 / 2 shared
Schenning, Albert P. H. J.
1 / 13 shared
Dasgupta, Debarshi
1 / 2 shared
Mulder, Dirk-Jan
1 / 2 shared
Arapov, Kirill A. Arapov Kirill
1 / 2 shared
Franeker, Jj Hans Van
1 / 4 shared
Michels, Jj
1 / 7 shared
Gommes, Cedric
2 / 4 shared
Janssen, Rene A. J.
2 / 12 shared
Kuropatwa, Bryan A.
1 / 1 shared
Pavlopoulou, Eleni
1 / 10 shared
Petsagkourakis, Ioannis
1 / 7 shared
Dilhaire, Stefan, A.
1 / 1 shared
Pape, A. C. H.
1 / 1 shared
Rowan, Alan E.
1 / 5 shared
Voets, Ilja K.
1 / 10 shared
Kouwer, Paul H. J.
1 / 4 shared
Jaspers, Maarten
1 / 3 shared
Wilsens, Carolus H. R. M.
1 / 2 shared
Pepels, Mark P. F.
1 / 3 shared
Deshmukh, Yogesh S.
1 / 2 shared
Auhl, Dietmar
1 / 18 shared
Harings, Jules A. W.
1 / 2 shared
Auriemma, Finizia
1 / 7 shared
Lazzari, Massimo
1 / 7 shared
Rosa, Claudio De
1 / 2 shared
Girolamo, Rocco Di
1 / 1 shared
Malafronte, Anna
1 / 5 shared
Hamley, Ian William
1 / 2 shared
Nieto-Suárez, Marina
1 / 2 shared
Melchior, Jan-Patrick
1 / 1 shared
Wohlfarth, Andreas
1 / 1 shared
Kreuer, Klaus-Dieter
1 / 1 shared
Bräuniger, Thomas
1 / 5 shared
Franeker, Jacobus J. Van
1 / 2 shared
Schaefer, Charley
1 / 5 shared
Wienk, Martijn M.
1 / 41 shared
Li, Weiwei
1 / 15 shared
Schoot, Paul Van Der
1 / 1 shared
Heintges, Gael H. L.
1 / 4 shared
Rueda, Daniel R.
1 / 14 shared
Rodríguez-Rodríguez, Álvaro
1 / 1 shared
Rebollar, Esther
1 / 21 shared
Ezquerra, Tiberio A.
1 / 43 shared
Castillejo, Marta
1 / 16 shared
García-Gutiérrez, Mari-Cruz
1 / 2 shared
Martín-Fabiani, Ignacio
1 / 13 shared
Mulder, Dirk J.
1 / 2 shared
Gelebart, Anne Helene
1 / 1 shared
Schenning, Albertus P. H. J.
1 / 7 shared
Leijten, J. W. A.
1 / 1 shared
Troisi, E. M.
1 / 2 shared
Ma, Z.
1 / 9 shared
Hermida-Merino, D.
1 / 7 shared
Drongelen, M. Van
1 / 1 shared
Peters, G. W. M.
1 / 30 shared
Albonetti, Cristiano
1 / 3 shared
Giannici, Francesco
1 / 14 shared
Biscarini, Fabio
1 / 7 shared
Sciortino, Luisa
1 / 8 shared
Martorana, Antonino
1 / 14 shared
Caelers, Harm J. M.
1 / 1 shared
Govaert, Leon E.
1 / 90 shared
Kanters, Marc J. W.
1 / 7 shared
Fields, Peter
1 / 1 shared
Vrolijk, Benno C. M.
1 / 1 shared
Wilson, Richard
1 / 3 shared
Dellar, Martin
1 / 1 shared
Jennings, James
1 / 3 shared
Caminiti, Ruggero
1 / 3 shared
Dilario, Lucio
1 / 4 shared
Martinelli, Andrea
1 / 7 shared
Albertini, Valerio Rossi
1 / 1 shared
Chart of publication period
2024
2023
2022
2021
2020
2019
2018
2017
2016
2015
2014
2007

Co-Authors (by relevance)

  • Tekelenburg, Eelco K.
  • Chen, Lijun
  • Loi, Maria Antonietta
  • Tran, Karolina
  • Brabec, Cj
  • Kooi, Bart Jan
  • Carlà, Francesco
  • Pinna, Jacopo
  • Pili, Elisa
  • Gavhane, Dnyaneshwar S.
  • Koushki, Razieh Mehrabi
  • Amirsadeghi, Armin
  • Dittberner, Olivia
  • Parisi, Daniele
  • Yunus, Roshan Akdar Mohamed
  • Van Westerveld, Larissa
  • Caïto, Clément
  • Calicchia, Eleonora
  • Maret, Denise
  • Arunachalam, Abinaya
  • Kamperman, Marleen
  • Sayed, Julien Es
  • Mario, Lorenzo Di
  • Mura, Andrea
  • Huitrón, Juan Carlos Alonso
  • Bongiovanni, Giovanni
  • Kahmann, Simon
  • Rivera-Medina, Martha J.
  • Hong, Jennifer
  • Mutalik, Suhas
  • Protesescu, Loredana
  • Gerlach, Dominic
  • Rudolf, Petra
  • Pescarmona, Paolo P.
  • Razieh Mehrabi, K.
  • Ahmadi, Majid
  • Miola, Matteo
  • Shao, Shuyan
  • Duim, Herman
  • Rommens, Alex J.
  • Jong, Leon De
  • Pelras, Théophile
  • Sacco, Federico Di
  • Jurewicz, Izabela
  • Keddie, Joseph L.
  • Munoz, Edgar
  • Howlin, Brendan J.
  • Huang, Zhiwei
  • Garriga, Rosa
  • Berg, Alexandra I.
  • Jonkman, Harry
  • Loos, Katja U.
  • Noheda, Beatriz
  • Tranchida, Davide
  • Kadar, Roland
  • Carmeli, Enrico
  • Cavallo, Dario
  • Gkourmpis, Thomas
  • Gitsas, Antonis
  • Frohna, Kyle
  • Duim, H.
  • Rommens, Aj
  • Ten Brink, Gert H.
  • Rommens, Alexander J.
  • Stranks, Samuel D.
  • Viviani, Marco
  • Lova, Paola
  • Baran, Derya
  • Villalva, Diego Rosas
  • Havenith, Remco W. A.
  • Dong, Jingjin
  • Qiu, Xinkai
  • Nugraha, Mohamad Insan
  • Koster, Lja
  • Sun, Hengda
  • Koopmans, Marten
  • Yao, Chen
  • Yang, Xuwen
  • Anthopoulos, Thomas D.
  • Potgieser, Hinderikus G. O.
  • Liu, Jian
  • Ye, Gang
  • Fabiano, Simone
  • Bras, Wim
  • Chapron, David
  • Saidi, Sarah
  • Amigo, José Manuel
  • Hermida-Merino, Daniel
  • Longo, Alessandro
  • Bourson, Patrice
  • Koutsogiannis, Panagiotis
  • Garcia Romero, David
  • Kamperman, Max
  • Zee, Bas Van Der
  • Villava, Diego R.
  • Hummelen, Jan
  • Fluitman, Sebastiaan Pieter
  • Pitaro, Matteo
  • Gahlot, Kushagra
  • Hadziioannou, Georges
  • Shi, Yulin
  • Pino, Guillaume
  • Demazy, Nils
  • Fleury, Guillaume
  • Mantione, Daniele
  • Cummins, Cian
  • Cruciani, Federico
  • Mulder, Pascal
  • Faraji, Shirin
  • Maniar, Dina
  • Golkaram, Milad
  • Leiviskä, Miina A. T.
  • Heiber, Michael C.
  • Gahleitner, Markus
  • Wang, Jingbo
  • Adjokatse, Sampson
  • Kloe, René De
  • Rousseva, Sylvia
  • Marrink, Siewert
  • Nugraha, Mohamad I.
  • Klasen, Nathalie
  • Caironi, Mario
  • Barker, Alex J.
  • Blake, Graeme R.
  • Groeneveld, Bart
  • Nazarenko, Olga
  • Kovalenko, Maksym
  • Meereboer, Niels L.
  • Terzic, Ivan
  • Ruymbeke, Evelyne Van
  • Fodor, Csaba
  • Boetje, Laura
  • Suarez, Luis Enrique Aguilar
  • Li, Ning
  • Spiecker, Erdmann
  • Ameri, Tayebeh
  • Perea, Jose Dario
  • Sperlich, Andreas
  • Salvador, Michael
  • Dyakonov, Vladimir
  • Gasparini, Nicola
  • Rechberger, Stefanie
  • Baumann, Andreas
  • Syariati, Ali
  • Heuver, Jeroen A.
  • Momand, Jamo
  • Varghese, Justin
  • Xu, Jin
  • Picot, Olivier
  • Gautrot, Julien E.
  • Crespo, Maria
  • Santagiuliana, Giovanni
  • Bilotti, Emiliano
  • Scheerder, Jurgen
  • Vagias, Apostolos
  • Chen, Qi
  • Howdle, Steven M.
  • Bassett, Simon P.
  • Bennett, Thomas M.
  • He, Guping
  • Alauhdin, Mohammad
  • Knudsen, Kenneth Dahl
  • Povia, Mauro
  • Margadonna, Serena
  • Sartori, Sabrina
  • Sottmann, Jonas
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article

Rapid Self-Assembly and Sequential Infiltration Synthesis of High χ Fluorine-Containing Block Copolymers

  • Hadziioannou, Georges
  • Shi, Yulin
  • Pino, Guillaume
  • Demazy, Nils
  • Fleury, Guillaume
  • Mantione, Daniele
  • Cummins, Cian
  • Cruciani, Federico
  • Portale, Giuseppe, A.
Abstract

<p>We leverage the attractive properties of a high χ-low N BCP, i.e., poly(styrene)-block-poly(2-fluoroethylmethyl acrylate) (PS-b-P2FEMA), and illustrate its utility for next-generation nanomanufacturing. The synthesis, physical characterization, and thin film self-assembly of a series of lamellar and cylindrical PS-b-P2FEMA BCPs are delineated. PS-b-P2FEMA BCPs with total molecular weights ranging from 7 to 22 kg mol-1 were synthesized by using reversible addition-fragmentation chain-transfer (RAFT) polymerization. Temperature-resolved small-angle X-ray scattering (SAXS) measurements revealed a large χ value (0.13 at 150 °C) for PS-b-P2FEMA. Solvothermal vapor annealing of PS-b-P2FEMA films produced highly oriented fingerprint patterns in as short as 60 s. Lamellar period sizes ranged from 25.9 down to 14.2 nm with feature sizes as small as 7 nm observed. We also demonstrate the integration feasibility of PS-b-P2FEMA BCPs through alumina hardmask formation using sequential infiltration synthesis. The highly favorable characteristics of the P2FEMA-based BCPs detailed here provide a versatile material option to the current library of available BCPs for sub-10 nm nanolithography. </p>

Topics
  • thin film
  • annealing
  • molecular weight
  • copolymer
  • block copolymer
  • small angle x-ray scattering
  • self-assembly