| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Lynd, Nathaniel A.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2020Spatial Control of the Self-assembled Block Copolymer Domain Orientation and Alignment on Photopatterned Surfacescitations
- 2020Unusual Thermal Properties of Certain Poly(3,5-disubstituted styrene)scitations
- 2018Shewanella oneidensis as a living electrode for controlled radical polymerizationcitations
- 2015A facile synthesis of catechol‐functionalized poly(ethylene oxide) block and random copolymerscitations
- 2008Polydispersity and block copolymer self-assemblycitations
- 2008Theory of polydisperse block copolymer meltscitations
- 2005Influence of polydispersity on the self-assembly of diblock copolymerscitations
Places of action
| Organizations | Location | People |
|---|
article
Unusual Thermal Properties of Certain Poly(3,5-disubstituted styrene)s
Abstract
<p>During the course of studying silicon-containing diblock copolymers, it was discovered that poly(3,5-di(trimethylsilyl)styrene)-block-poly(3,4-methylenedioxystyrene) (PDTMSS-b-PMDOS) showed very unusual thermal properties. The material can be recovered as a free-flowing powder despite heating above 250 °C. To better understand this behavior, homopolymers of the 3,5-disubstituted styrenes, poly(3,5-di(trimethylsilyl)styrene) (PDTMSS) and poly(3,5-di-tert-butylstyrene) (PDtBS), were prepared. These polymers are soluble in common organic solvents and formed clear, glassy thin films upon spin coating. These homopolymers were studied by differential scanning calorimetry (DSC), broadband dielectric spectroscopy (BDS), dynamic mechanical analysis (DMA), and temperature-programmed ellipsometry. These experiments document the lack of a conventional glass transition in these materials below their decomposition temperature. A series of statistical copolymers of PDTMSS and PDtBS with styrene was synthesized and studied by DSC in an attempt to establish the Tg of the homopolymers by model-based extrapolation.</p>