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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kooij, Ernst Stefan
University of Twente
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2019Brush Swelling and Attachment Strength of Barnacle Adhesion Protein on Zwitterionic Polymer Films as a Function of Macromolecular Structurecitations
- 2015Colloidal Route to Bio-inspired Hierarchical Superhydrophobic Substrates
- 2015Amplified responsiveness of multi-layered, polymer grafts: Synergy between brushes and hydrogelscitations
- 2015Innovative gold nanoparticle patterning and selective metallization
- 2013Selective metallization by seeded growth on patterned gold nanoparticle arrayscitations
- 2011Novel, highly selective gold nanoparticle patterning on surfaces using pure watercitations
- 2011Dielectrophoretic alignment of metal and metal oxide nanowires and nanotubescitations
- 2008Field induced phase segregation in ferrofluidscitations
- 2006Seeded-Growth Approach to Selective Metallization of Microcontact-Printed Patternscitations
- 2005Photoluminescence from undoped silicon after chemical etching combined with metal platingcitations
- 2004Electrochemically Induced Morphology and Volume Changes in Surface-Grafted Poly(ferrocenyldimethylsilane) Monolayerscitations
- 2004Ellipsometric characterisation of heterogeneous 2D layerscitations
- 2003Structural and optical characterization of porous anodic aluminium oxidecitations
- 2002Hysteresis in YHx films observed with in situ measurementscitations
- 2001Structural, electrical, and optical properties of La1-z YzHx switchable mirrorscitations
- 2001Structural, optical and electronic properties of LaMgHx switchable mirrorscitations
- 2000Quenching of Giant Hysteresis Effects in La1-zYzHx Switchable Mirrorscitations
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article
Brush Swelling and Attachment Strength of Barnacle Adhesion Protein on Zwitterionic Polymer Films as a Function of Macromolecular Structure
Abstract
<p>The exceptional hydration of sulfobetaine polymer brushes and their resistance toward nonspecific protein absorption allows for the construction of thin films with excellent antibiofouling properties. In this work, swollen sulfobetaine brushes, prepared by surface-initiated atom transfer radical polymerization of two monomers, differentiated by the nature of the polymerizable group, are studied and compared by a liquid-cell atomic force microscopy technique and spectroscopic ellipsometry. Colloidal AFM-based force spectroscopy is employed to estimate brush grafting density and characterize nanomechanical properties in salt water. When the ionic strength-induced swelling behaviors of the two systems are compared, the differences observed on the antipolyelectrolyte response can be correlated with the stiffness variation on brush compression, likely to be promoted by solvation differences. The higher solvation of amide groups is proposed to be responsible for the lower adhesion force of the barnacle cyprid's temporary adhesive proteins. The adhesion results provide further insights into the antibiofouling activity against barnacle cyprid settlement attributed to polysulfobetaine brushes.</p>