Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (3/3 displayed)

  • 2016Lipid spontaneous curvatures estimated from temperature-dependent changes in inverse hexagonal phase lattice parameters: effects of metal cations16citations
  • 2014Formation of inverse topology lyotropic phases in dioleoylphosphatidylcholine/oleic acid and dioleoylphosphatidylethanolamine/oleic acid binary mixtures24citations
  • 2014Development of a novel bio-compatible polymer film for use as a Bruch’s membrane substitutecitations

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Chart of shared publication
Gillams, Richard J.
2 / 2 shared
Nylander, Tommy
2 / 21 shared
Labrador, Ana
1 / 2 shared
Dymond, Marcus K.
2 / 2 shared
Parker, Duncan
1 / 1 shared
Burrell, James
1 / 1 shared
Plivelic, Tomás S.
1 / 10 shared
Ward, Gareth
1 / 1 shared
Grossel, Martin C.
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Alexander, Philip
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Treharne, Andrew
1 / 1 shared
Ratnayaka, J. Arjuna
1 / 2 shared
Lotery, Andrew
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Thomson, Heather
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2016
2014

Co-Authors (by relevance)

  • Gillams, Richard J.
  • Nylander, Tommy
  • Labrador, Ana
  • Dymond, Marcus K.
  • Parker, Duncan
  • Burrell, James
  • Plivelic, Tomás S.
  • Ward, Gareth
  • Grossel, Martin C.
  • Alexander, Philip
  • Treharne, Andrew
  • Ratnayaka, J. Arjuna
  • Lotery, Andrew
  • Thomson, Heather
OrganizationsLocationPeople

article

Lipid spontaneous curvatures estimated from temperature-dependent changes in inverse hexagonal phase lattice parameters: effects of metal cations

  • Gillams, Richard J.
  • Nylander, Tommy
  • Attard, George
  • Labrador, Ana
  • Dymond, Marcus K.
  • Parker, Duncan
  • Burrell, James
Abstract

Recently we reported a method for estimating the spontaneous curvatures of lipids from temperature-dependent changes in the lattice parameter of inverse hexagonal liquid crystal phases of binary lipid mixtures. This method makes use of 1,2-dioleoyl-sn-glycerol-3-phosphoethanolamine (DOPE) as a host lipid, which preferentially forms an inverse hexagonal phase to which a guest lipid of unknown spontaneous curvature is added. The lattice parameters of these binary lipid mixtures are determined by small-angle X-ray diffraction at a range of temperatures and the spontaneous curvature of the guest lipid is determined from these data. Here we report the use of this method on a wide range of lipids under different ionic conditions. We demonstrate that our method provides spontaneous curvature values for DOPE, cholesterol, and monoolein that are within the range of values reported in the literature. Anionic lipids 1,2-dioleoyl-sn-glycerol-3-phosphatidic acid (DOPA) and 1,2-dioleoyl-sn-glycerol-3-phosphoserine (DOPS) were found to exhibit spontaneous curvatures that depend on the concentration of divalent cations present in the mixtures. We show that the range of curvatures estimated experimentally for DOPA and DOPS can be explained by a series of equilibria arising from lipid-cation exchange reactions. Our data indicate a universal relationship between the spontaneous curvature of a lipid and the extent to which it affects the lattice parameter of the hexagonal phase of DOPE when it is part of a binary mixture. This universal relationship affords a rapid way of estimating the spontaneous curvatures of lipids that are expensive, only available in small amounts, or are of limited chemical stability.

Topics
  • impedance spectroscopy
  • phase
  • chemical stability
  • liquid crystal
  • small-angle X-ray diffraction