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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zhang, Lin
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Oxygen concentration – a governing parameter for microstructural tailoring of duplex AlCrSiON coatings for superior mechanical, tribological, and anti-corrosion performancecitations
- 2021Designing tubular conducting polymer actuators for wireless electropumpingcitations
- 2019CO2 photoelectrochemical reduction in room-temperature ionic liquids-based media evaluated by Scanning Electrochemical Microscopy
- 2018Locally Addressed Photoelectrocatalysts for CO2 Reduction in NonconventionalSolvents
- 2016Electrografting of 3-Aminopropyltriethoxysilane on a Glassy Carbon Electrode for the Improved Adhesion of Vertically Oriented Mesoporous Silica Thin Filmscitations
- 2014Perceived and performance-based executive dysfunction in Parkinson's diseasecitations
- 2014Anisotropic elasticity of silicon and its application to the modelling of X-ray opticscitations
- 2009Sensing properties of germanate and tellurite glass optical fibrescitations
- 2009Fiber Bragg gratings inscribed using 800nm femtosecond laser and a phase mask in singleand multi-core mid-IR glass fibers
- 2009Fiber Bragg gratings inscribed using 800nm femtosecond laser and a phase mask in single- And multi-core mid-IR glass fiberscitations
- 2005Strain and temperature sensitivity of a single-mode polymer optical fibercitations
- 2005Strain and temperature sensitivity of a single-mode polymer optical fiber
- 2000First in-vivo trials of a fibre Bragg grating based temperature profiling systemcitations
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article
Electrografting of 3-Aminopropyltriethoxysilane on a Glassy Carbon Electrode for the Improved Adhesion of Vertically Oriented Mesoporous Silica Thin Films
Abstract
Vertically oriented mesoporous silica has proven to be of interest for applications in a variety of fields (e.g., electroanalysis, energy, and nanotechnology). Although glassy carbon is widely used as an electrode material, the adherence of silica deposits is rather poor, causing mechanical instability. A solution to improve the adhesion of mesoporous silica films onto glassy carbon electrodes without compromising the vertical orientation and the order of the mesopores will greatly contribute to the use of this kind of modified carbon electrode. We propose here the electrografting of 3-amino-propyltriethoxysilane on glassy carbon as a molecular glue to improve the mechanical stability of the silica film on the electrode surface without disturbing the vertical orientation and the order of the mesoporous silica obtained by electrochemically assisted self-assembly. These findings are supported by a series of surface chemistry techniques such as X-ray photoelectron spectroscopy, scanning and transmission electron microscopy, and cyclic voltammetry. Finally, methylviologen was used as a model redox probe to investigate the cathodic potential region of both glassy carbon and indium tin oxide electrodes modified with mesoporous silica in order to demonstrate further the interest in the approach developed here.