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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Almora Rodríguez, Osbel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Ion Migration and Space-Charge Zones in Metal Halide Perovskites Through Short-Circuit Transient Current and Numerical Simulationscitations
- 2023Long-term field screening by mobile ions in thick metal halide perovskites: understanding saturation currentscitations
- 2023Ionic Field Screening in MAPbBr3 Crystals Revealed from Remnant Sensitivity in X-ray Detectioncitations
- 2023Effective Ion Mobility and Long-Term Dark Current of Metal Halide Perovskites with Different Crystallinities and Compositionscitations
- 2022High-sensitivity high-resolution X-ray imaging with soft-sintered metal halide perovskitescitations
- 2021Mobile Ion-Driven Modulation of Electronic Conductivity Explains Long-Timescale Electrical Response in Lead Iodide Perovskite Thick Pelletscitations
- 2021Characterization of Aerosol Deposited Cesium Lead Tribromide Perovskite Films on Interdigited ITO Electrodescitations
- 2019Light Capacitances in Silicon and Perovskite Solar Cellscitations
- 2019Utilization of Temperature-Sweeping Capacitive Techniques to Evaluate Band Gap Defect Densities in Photovoltaic Perovskitescitations
- 2019Electrical-field driven tunable spectral responses in a broadband-absorbing perovskite photodiodecitations
- 2018Superior Performance of V2O5 as Hole Selective Contact over other Transition Metal Oxides in Silicon Heterojunction Solar Cellscitations
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article
Utilization of Temperature-Sweeping Capacitive Techniques to Evaluate Band Gap Defect Densities in Photovoltaic Perovskites
Abstract
Capacitive techniques, routinely used for solar cell parameter extraction, probe the voltage-modulation of the depletion layer capacitance isothermally as well as under varying temperature. Also defect states within the semiconductor band-gap respond to such stimuli. Although extensively used, capacitive methods have found difficulties when applied to elucidate bulk defect bands in photovoltaic perovskites. This is so because perovskite solar cells (PSCs) actually exhibit some intriguing capacitive features hardly connected to electronic defect dynamics. The commonly reported excess capacitance observed at low frequencies is originated by outer interface mechanisms and has a direct repercussion on the evaluation of band-gap defect levels. Starting by updating previous observations on Mott-Schottky (MS) analysis in PSCs, it is discussed how the thermal admittance spectroscopy (TAS) and the deep level transient spectroscopy (DLTS) characterization techniques present spectra with overlapping or even “fake” peaks caused by the mobile ion-related, interfacial excess capacitance. These capacitive techniques, when used uncritically, may be misleading and produce wrong outcomes.