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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Yin, Jun
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Anisotropic Superconducting Nb<sub>2</sub>CT<i><sub>x</sub></i> MXene Processed by Atomic Exchange at The Wafer Scalecitations
- 2023State of the Art and Prospects for Halide Perovskite Nanocrystals.
- 2023Zero-dimensional Cu(i)-based organometallic halide with green cluster-centred emission for high resolution X-ray imaging screenscitations
- 2021State of the art and prospects for halide perovskite nanocrystalscitations
- 2021State of the art and prospects for halide perovskite nanocrystalscitations
- 2020Large Polaron Self-Trapped States in Three-Dimensional Metal-Halide Perovskitescitations
- 2019Planar and van der Waals heterostructures for vertical tunnelling single electron transistorscitations
- 2018Ligand-Free Nanocrystals of Highly Emissive Cs4PbBr6 Perovskitecitations
- 2018Characterization of the Valence and Conduction Band Levels of n = 1 2D Perovskites: A Combined Experimental and Theoretical Investigationcitations
- 2018Growth of graphene on tantalum and its protective propertiescitations
- 2017Ultralow Self-Doping in 2D Hybrid Perovskite Single Crystalscitations
- 2017Ultralong Radiative States in Hybrid Perovskite Crystals: Compositions for Submillimeter Diffusion Lengthscitations
- 2015Surface electrical properties of stainless steel fibres: An AFM-based studycitations
- 2012Metal condensates for low-molecular-weight matrix-free laser desorption/ionizationcitations
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article
Ultralong Radiative States in Hybrid Perovskite Crystals: Compositions for Submillimeter Diffusion Lengths
Abstract
Organic-inorganic hybrid perovskite materials have recently evolved into the leading candidate solution-processed semiconductor for solar cells due to their combination of desirable optical and charge transport properties. Chief among these properties is the long carrier diffusion length, which is essential to optimizing the device architecture and performance. Herein, we used time-resolved photoluminescence (at low excitation fluence, 10.59 μJ·cm upon two-photon excitation), which is the most accurate and direct approach to measure the radiative charge carrier lifetime and diffusion lengths. Lifetimes of about 72 and 4.3 μs for FAPbBr and FAPbI perovskite single crystals have been recorded, presenting the longest radiative carrier lifetimes reported to date for perovskite materials. Subsequently, carrier diffusion lengths of 107.2 and 19.7 μm are obtained. In addition, we demonstrate the key role of the organic cation units in modulating the carrier lifetime and its diffusion lengths, in which the defect formation energies for FA cations are much higher than those with the MA ones.