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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Grosu, Yaroslav
CIC energiGUNE
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2024Local grafting heterogeneities control water intrusion and extrusion in nanoporescitations
- 2024Partial water intrusion and extrusion in hydrophobic nanopores for thermomechanical energy dissipationcitations
- 2024Tuning Wetting–Dewetting Thermomechanical Energy for Hydrophobic Nanopores via Preferential Intrusioncitations
- 2024Tuning Wetting–Dewetting Thermomechanical Energy for Hydrophobic Nanopores via Preferential Intrusioncitations
- 2024Effect of linker hybridization on the wetting of hydrophobic metal-organic frameworkscitations
- 2024Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu2(tebpz) MOFcitations
- 2024Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu<sub>2</sub>(tebpz) MOFcitations
- 2024Mild-Temperature Supercritical Water Confined in Hydrophobic Metal–Organic Frameworkscitations
- 2024Pulsating heat pipe performance enhancement through porous metallic surfaces produced via physical dealloyingcitations
- 2024Pulsating heat pipe performance enhancement through porous metallic surfaces produced via physical dealloyingcitations
- 2023The impact of secondary channels on the wetting properties of interconnected hydrophobic nanoporescitations
- 2023Effect of Crystallite Size on the Flexibility and Negative Compressibility of Hydrophobic Metal–Organic Frameworkscitations
- 2022Effect of the Topology on Wetting and Drying of Hydrophobic Porous Materialscitations
- 2022Turning Molecular Springs into Nano-Shock Absorbers: The Effect of Macroscopic Morphology and Crystal Size on the Dynamic Hysteresis of Water Intrusion-Extrusion into-from Hydrophobic Nanoporescitations
- 2022Turning Molecular Springs into Nano-Shock Absorbers: The Effect of Macroscopic Morphology and Crystal Size on the Dynamic Hysteresis of Water Intrusion-Extrusion into-from Hydrophobic Nanoporescitations
- 2022Experimental investigation of erosion due to nanofluidscitations
- 2022Turning Molecular Springs into Nano-Shock Absorbers: The Effect of Macroscopic Morphology and Crystal Size on the Dynamic Hysteresis of Water Intrusion-Extrusion into-from Hydrophobic Nanopores.
- 2022Subnanometer Topological Tuning of the Liquid Intrusion/Extrusion Characteristics of Hydrophobic Microporescitations
- 2021The effect of surface entropy on the heat of non-wetting liquid intrusion into nanoporescitations
- 2021Liquid intrusion in and extrusion from non-wettable nanopores for technological applicationscitations
- 2020Synthesis of high temperature TES materials from silicates wastes for application in solar tower power plantscitations
- 2020Inhibiting hot corrosion of molten Li2CO3-Na2CO3-K2CO3 salt through graphitization of construction materials for concentrated solar powercitations
- 2019Pore Morphology Determines Spontaneous Liquid Extrusion from Nanoporescitations
- 2018Viscosity at the nanoscale: confined liquid dynamics and thermal effects in self-recovering nanobumperscitations
Places of action
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article
Tuning Wetting–Dewetting Thermomechanical Energy for Hydrophobic Nanopores via Preferential Intrusion
Abstract
Heat and the work of compression/decompression are among the basic properties of thermodynamic systems. Being relevant to many industrial and natural processes,this thermomechanical energy is challenging to tune due to fundamental boundaries for simple fluids. Here via direct experimental and atomistic observations, we demonstrate, for fluids consisting of nanoporous material and a liquid, one can overcome these limitations and noticeably affect both thermal and mechanical energies of compression/decompression exploiting preferential intrusion of water from aqueous solutions into subnanometer pores. We hypothesize that this effect is due to the enthalpy of dilution manifesting itself as the aqueous solution concentrates upon the preferential intrusion of pure water into pores. We suggest this genuinely subnanoscale phenomenon can be potentially a strategy for controlling the thermomechanical energy of microporous liquids and tuning the wetting/dewetting heat of nanopores relevant to a variety of natural and technological processes spanning from biomedical applications to oil-extraction and renewable energy.