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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bai, Yang
University of Edinburgh
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Study on Growth of Tungsten Bronze Phase from Niobate Perovskite Ceramics in Controlled Atmosphere for Photoferroelectric Applicationscitations
- 2022Hierarchical nature of hydrogen-based direct reduction of iron oxidescitations
- 2021Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2021Time-resolved Raman spectroscopy of polaron formation in a polymer photocatalystcitations
- 2021Hierarchical bismuth vanadate/reduced graphene oxide composite photocatalyst for hydrogen evolution and bisphenol A degradationcitations
- 2021Formulation, adsorption performance, and mechanical integrity of triamine grafted binder-based mesoporous silica pellets for CO2 capturecitations
- 2020Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2020Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2019New ferroelectric perovskite ceramics with low losses for applications in microwave antennas
Places of action
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article
Time-resolved Raman spectroscopy of polaron formation in a polymer photocatalyst
Abstract
Polymer photocatalysts are a synthetically diverse class of materials that can be used for the production of solar fuels such as H2, but the underlying mechanisms by which they operate are poorly understood. Time-resolved vibrational spectroscopy provides a powerful structure-specific probe of photogenerated species. Here we report the use of time-resolved resonance Raman (TR3) spectroscopy to study the formation of polaron pairs and electron polarons in one of the most active linear polymer photocatalysts for H2 production, poly(dibenzo[b,d]thiophene sulfone), P10. We identify that polaron-pair formation prior to thermalization of the initially generated excited states is an important pathway for the generation of long-lived photoelectrons.