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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gall, Florence Bally-Le
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Publications (7/7 displayed)
- 2023Fluorine-Free Plasma Polymers to Obtain Water-Repellent Cotton Fabrics: How to Control Their Durability?citations
- 2021Unique combination of spatial and temporal control of maleic anhydride plasma polymerizationcitations
- 2020When chemistry of the substrate drastically controls morphogenesis of plasma polymer thin filmscitations
- 2019Interfacial Diels–Alder Reaction between Furan-Functionalized Polymer Coatings and Maleimide-Terminated Poly(ethylene glycol)citations
- 2017Polylutidinescitations
- 2016Textile with Durable Janus Wetting Properties Produced by Plasma Polymerizationcitations
- 2015Free-Standing Nanomembranes Based on Selective CVD Deposition of Functional Poly- p -xylylenescitations
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article
Interfacial Diels–Alder Reaction between Furan-Functionalized Polymer Coatings and Maleimide-Terminated Poly(ethylene glycol)
Abstract
Surface functionalization is an interesting way to elaborate new smart materials. In this work, a two-step surface modification, based on pulsed plasma polymerization, was used to design functional surfaces able to react by Diels–Alder reaction (a diene–dienophile cycloaddition). The reactivity of furan-functionalized (diene) surfaces with a maleimide-derivative (dienophile) was studied. The determination of the rate constants led to the determination of the activation energy, the enthalpy of activation, and the entropy of activation. These results were then compared to those obtained in solution. For the first time, it was possible to understand the role played by molecule confinement (close to the surface) on the Diels–Alder reactivity.