| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Roucoules, Vincent
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2023Morphology of ultrathin gold and copper coatings thermally evaporated on polydimethylsiloxane elastomers: from isolated nanoparticles to continuous coatingscitations
- 2023Fluorine-Free Plasma Polymers to Obtain Water-Repellent Cotton Fabrics: How to Control Their Durability?citations
- 2023Fluorine-Free Plasma Polymers to Obtain Water-Repellent Cotton Fabrics: How to Control Their Durability?citations
- 2021Unique combination of spatial and temporal control of maleic anhydride plasma polymerizationcitations
- 2021Mechanical properties of plasma polymer films: a reviewcitations
- 2020When chemistry of the substrate drastically controls morphogenesis of plasma polymer thin filmscitations
- 2020When chemistry of the substrate drastically controls morphogenesis of plasma polymer thin filmscitations
- 2019Interfacial Diels–Alder Reaction between Furan-Functionalized Polymer Coatings and Maleimide-Terminated Poly(ethylene glycol)citations
- 2019Interfacial Diels–Alder Reaction between Furan-Functionalized Polymer Coatings and Maleimide-Terminated Poly(ethylene glycol)citations
- 2017Macroscopic control of DMAHEMA and HEMA plasma polymerization to tune the surface mechanical properties of hydrogel-like coatingscitations
- 2016Stability of Plasma Treated Non-vulcanized Polybutadiene Surfaces: Role of Plasma Parameters and Influence of Additivescitations
- 2016Textile with Durable Janus Wetting Properties Produced by Plasma Polymerizationcitations
- 2016Textile with Durable Janus Wetting Properties Produced by Plasma Polymerizationcitations
- 2016Stability of maleic anhydride plasma polymer film to water drop evaporationcitations
- 2015Role of Cellulose Nanocrystals on the Microstructure of Maleic Anhydride Plasma Polymer Thin Filmscitations
- 2015Influence of Plasma Chamber Set-Up on the Surface Modification of Non-Vulcanized and Pure SBR Rubber Treated at Radio-Frequencies Air Plasmacitations
- 2014Use of Plasma Polymerization to Improve Adhesion Strength in Carbon Fiber Composites Cured by Electron Beamcitations
- 2013Influence of Covalent Bonds on the Adhesion Energy at Elastomer-Glass Interfacescitations
- 2012Metastable Patterning of Plasma Nanocomposite Films by Incorporating Cellulose Nanowhiskerscitations
- 2009Plasma polymer films with controlled topography and chemistry at the nanoscale
Places of action
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article
Interfacial Diels–Alder Reaction between Furan-Functionalized Polymer Coatings and Maleimide-Terminated Poly(ethylene glycol)
Abstract
Surface functionalization is an interesting way to elaborate new smart materials. In this work, a two-step surface modification, based on pulsed plasma polymerization, was used to design functional surfaces able to react by Diels–Alder reaction (a diene–dienophile cycloaddition). The reactivity of furan-functionalized (diene) surfaces with a maleimide-derivative (dienophile) was studied. The determination of the rate constants led to the determination of the activation energy, the enthalpy of activation, and the entropy of activation. These results were then compared to those obtained in solution. For the first time, it was possible to understand the role played by molecule confinement (close to the surface) on the Diels–Alder reactivity.