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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sartori, Sabrina
University of Oslo
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2023The Effect of Y Content on Structural and Sorption Properties of A2B7-Type Phase in the La–Y–Ni–Al–Mn System ; ENEngelskEnglishThe Effect of Y Content on Structural and Sorption Properties of A2B7-Type Phase in the La–Y–Ni–Al–Mn Systemcitations
- 2023The Effect of Y Content on Structural and Sorption Properties of A2B7-Type Phase in the La–Y–Ni–Al–Mn Systemcitations
- 2022Magnesium- and intermetallic alloys-based hydrides for energy storage:Modelling, synthesis and propertiescitations
- 2022Magnesium- and intermetallic alloys-based hydrides for energy storage : modelling, synthesis and propertiescitations
- 2022Magnesium- and intermetallic alloys-based hydrides for energy storage: modelling, synthesis and properties ; ENEngelskEnglishMagnesium- and intermetallic alloys-based hydrides for energy storage: modelling, synthesis and propertiescitations
- 2022Magnesium- and intermetallic alloys-based hydrides for energy storage: modelling, synthesis and propertiescitations
- 2020Preferential Orientation of Photochromic Gadolinium Oxyhydride Filmscitations
- 2020Preferential Orientation of Photochromic Gadolinium Oxyhydride Filmscitations
- 2019Effect of ball milling and cryomilling on the microstructure and first hydrogenation properties of TiFe + 4 wt.% Zr alloycitations
- 2019Application of hydrides in hydrogen storage and compression:Achievements, outlook and perspectivescitations
- 2019Mechanochemistry of Metal Hydrides:Recent Advancescitations
- 2019Application of Hydrides in Hydrogen Storage and Compression: Achievements, Outlook and Perspectivescitations
- 2019Mechanochemistry of metal hydrides: Recent advancescitations
- 2019Application of hydrides in hydrogen storage and compression: achievements, outlook and perspectivescitations
- 2018Effect of Al presence and synthesis method on phase composition of the hydrogen absorbing La–Mg–Ni-based compounds ; ENEngelskEnglishEffect of Al presence and synthesis method on phase composition of the hydrogen absorbing La–Mg–Ni-based compoundscitations
- 2018Operando SAXS/WAXS on the a-P/C as the Anode for Na-Ion Batteriescitations
- 2006Hydrogen storage in Mg-Ni-Fe compounds prepared by melt spinning and ball millingcitations
Places of action
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article
Operando SAXS/WAXS on the a-P/C as the Anode for Na-Ion Batteries
Abstract
A complete chemical and morphological analysis of the evolution of battery electrode materials can be achieved combining different and complementary techniques. Operando small-angle X-ray scattering (SAXS) and wide-angle X-ray scattering (WAXS) were combined to investigate structural and electrochemical performances of an Na-ion battery, with amorphous red phosphorus in a carbon matrix (a-P/C) as the active anode material in a Swagelok-type cell. The charging process results in the formation of crystalline Na3P, while during discharging, the anode material returns to the initial a-P/C. From the analysis of the WAXS curves, the formation of crystalline phases appears only at the end of charging. However, SAXS data show that partial reorganization of the material during charging occurs at length scales nonaccessible with conventional X-ray diffraction, corresponding to a real space ordering distance of 4.6 nm. Furthermore, the analysis of the SAXS data shows that the electrode remains dense during charging, while it develops some porosity during the discharge phase. The presented results indicate that the combination of SAXS/WAXS adopted simultaneously, and nondestructively, on a working electrochemical cell can highlight new mechanisms of reactions otherwise undetected. This method can be applied for the study of any other solid electrode material for batteries.