| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mølhave, Kristian S.
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Microheater Controlled Crystal Phase Engineering of Nanowires Using In Situ Transmission Electron Microscopycitations
- 2024Microheater Controlled Crystal Phase Engineering of Nanowires Using In Situ Transmission Electron Microscopycitations
- 2024Operando Electron Microscopy and Impedance Analysis of Solid Oxide Electrolysis and Fuel Cellscitations
- 2021Development of high-temperature electrochemical TEM and its application on solid oxide electrolysis cells
- 2021Initiation and Progression of Anisotropic Galvanic Replacement Reactions in a Single Ag Nanowirecitations
- 2020Complex Aerosol Characterization by Scanning Electron Microscopy Coupled with Energy Dispersive X-ray Spectroscopycitations
- 2018Influence of Cetyltrimethylammonium Bromide on Gold Nanocrystal Formation Studied by in Situ Liquid Cell Scanning Transmission Electron Microscopycitations
- 2017Direct bonding of ALD Al2O3 to silicon nitride thin filmscitations
- 2016Controlling nanowire growth through electric field-induced deformation of the catalyst dropletcitations
- 2016In-Situ Transmission Electron Microscopy on Operating Electrochemical Cells
- 2016Effect of Synthesis Parameters on the Structure and Magnetic Properties of Magnetic Manganese Ferrite/Silver Composite Nanoparticles Synthesized by Wet Chemistry Methodcitations
- 2015Feasibility of the development of reference materials for the detection of Ag nanoparticles in food: neat dispersions and spiked chicken meatcitations
- 2011Titanium tungsten coatings for bioelectrochemical applications
- 2010Customizable in situ TEM devices fabricated in freestanding membranes by focused ion beam millingcitations
- 2008Epitaxial Integration of Nanowires in Microsystems by Local Micrometer Scale Vapor Phase Epitaxycitations
- 2003Soldering of Nanotubes onto Microelectrodescitations
- 2003Solid gold nanostructures fabricated by electron beam depositioncitations
- 2001Customizable nanotweezers for manipulation of free-standing nanostructurescitations
Places of action
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article
Influence of Cetyltrimethylammonium Bromide on Gold Nanocrystal Formation Studied by in Situ Liquid Cell Scanning Transmission Electron Microscopy
Abstract
The synthesis of monodisperse size- and shape-controlled Au nanocrystals is often achieved with cetyltrimethylammonium bromide (CTAB) surfactant; however, its role in the growth of such tailored nanostructures is not well understood. To elucidate the formation mechanism(s) and evolution of the morphology of Au nanocrystals in the early growth stage, we present an in situ liquid-cell scanning transmission electron microscopy (STEM) investigation using electron beam-induced radiolytic species as the reductant. The resulting particle shape at a low beam dose rate is shown to be strongly influenced by the surfactant; the Au nanocrystal growth rate is suppressed by increasing the CTAB concentration. At a low CTAB concentration, the nanoparticles (NPs) follow a reaction-limited growth mechanism, while at high a CTAB concentration the NPs follow a diffusion-limited mechanism, as described by the Lifshitz-Slyozov-Wagner (LSW) model. Moreover, we investigate the temporal evolution of specific NP geometries. The amount of Au reduced by the electron beam outside the irradiated area is quantified to better interpret the nanocrystal growth kinetics, as well as to further develop an understanding of electron beam interactions with nanomaterials toward improving the interpretation of in situ measurements.