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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Ayala, Paola
University of Vienna
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Temperature dependence of the Raman spectrum of orthorhombic Bi2Se3
- 2022Highly Sensitive and Selective Formaldehyde Gas Sensors Based on Polyvinylpyrrolidone/Nitrogen-Doped Double-Walled Carbon Nanotubescitations
- 2021The influence of Cr and Ni doping on the microstructure of oxygen containing diamond-like carbon filmscitations
- 2021Photothermal synthesis of confined carbynecitations
- 2019Roles of Precursor Conformation and Adatoms in Ullmann Coupling: An Inverted Porphyrin on Cu(111)citations
- 2019Towards controllable inner chirality in double-walled carbon nanotubescitations
- 2016Disentangling Vacancy Oxidation on Metallicity-Sorted Carbon Nanotubescitations
- 2013Hybrid Carbon Nanotube Networks as Efficient Hole Extraction Layers for Organic Photovoltaicscitations
- 2011Nitrogen-Doped Single-Walled Carbon Nanotube Thin Films Exhibiting Anomalous Sheet Resistancescitations
- 2011Mechanism of the initial stages of nitrogen-doped single-walled carbon nanotube growthcitations
- 2010Evidence for substitutional boron in doped single-walled carbon nanotubescitations
- 2009Carbon nanotube synthesis via ceramic catalystscitations
- 2008A one step approach to B-doped single-walled carbon nanotubescitations
Places of action
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article
Disentangling Vacancy Oxidation on Metallicity-Sorted Carbon Nanotubes
Abstract
<p>Pristine single-walled carbon nanotubes (SWCNTs) are rather inert to O<sub>2</sub> and N<sub>2</sub>, which for low doses chemisorb only on defect sites or vacancies of the SWCNTs at the ppm level. However, very low doping has a major effect on the electronic properties and conductivity of the SWCNTs. Already at low O<sub>2</sub> doses (80 L), the X-ray photoelectron spectroscopy (XPS) O 1s signal becomes saturated, indicating nearly all of the SWCNT's vacancies have been oxidized. As a result, probing vacancy oxidation on SWCNTs via XPS yields spectra with rather low signal-to-noise ratios, even for metallicity-sorted SWCNTs. We show that, even under these conditions, the first-principles density functional theory calculated Kohn-Sham O 1s binding energies may be used to assign the XPS O 1s spectra for oxidized vacancies on SWCNTs into its individual components. This allows one to determine the specific functional groups or bonding environments measured. We find the XPS O 1s signal is mostly due to three O-containing functional groups on SWCNT vacancies: epoxy (C<sub>2</sub>>O), carbonyl (C<sub>2</sub>>C=O), and ketene (C=C=O), as ordered by abundance. Upon oxidation of nearly all of the SWCNT's vacancies, the central peak's intensity for the metallic SWCNT sample is 60% greater than that for the semiconducting SWCNT sample. This suggests a greater abundance of O-containing defect structures on the metallic SWCNT sample. For both metallic and semiconducting SWCNTs, we find O<sub>2</sub> does not contribute to the measured XPS O 1s spectra.</p>