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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Grillo, Federico
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Molecularly Imprinted Viral Protein Integrated Zn−Cu−In−Se−P Quantum Dots Superlattice for Quantitative Ratiometric Electrochemical Detection of SARS-CoV‑2 Spike Protein in Salivacitations
- 2024Molecularly Imprinted Viral Protein Integrated Zn-Cu-In-Se-P Quantum Dots Superlattice for Quantitative Ratiometric Electrochemical Detection of SARS-COV-2 Spike Protein in Salivacitations
- 2024Molecularly imprinted viral protein integrated Zn-Cu-In-Se-P quantum dots superlattice for quantitative ratiometric electrochemical detection of SARS-CoV-2 spike protein in salivacitations
- 2024Understanding the passivation layer formed by tolyltriazole on copper, bronze, and brass surfaces
- 2024Understanding the passivation layer formed by tolyltriazole on copper, bronze, and brass surfaces
- 2022Highly ordered N-heterocyclic carbene monolayers on Cu(111)citations
- 2022Highly ordered N-heterocyclic carbene monolayers on Cu(111)citations
- 2022Surface confined hydrogenation of graphene nanoribbonscitations
- 2022Adsorption of the prototypical organic corrosion inhibitor benzotriazole on the Cu(100) surfacecitations
- 2022Understanding the interaction of organic corrosion inhibitors with copper at the molecular scale : benzotriazole on Cu(110)citations
- 2021Understanding the interaction of organic corrosion inhibitors with copper at the molecular scale:benzotriazole on Cu(110)citations
- 2020On-surface condensation of low-dimensional benzotriazole–copper assembliescitations
- 2019Calculating the frequencies and intensities of strongly anharmonic modes of adsorbates on surfacescitations
- 2019A Corrosion Inhibitor on Metal Surfaces
- 2019On-surface condensation of low-dimensional benzotriazole–copper assembliescitations
- 2016Metallosupramolecular assembly of Cr and p-terphenylnitrile by dissociation of metal carbonyls on Au(111)citations
- 2014Passivation of Copper: Benzotriazole Films on Cu (111)citations
- 2012An ordered organic radical adsorbed on a Cu-doped Au(111) surfacecitations
- 2007NSR catalysis studied using scanning tunnelling microscopycitations
Places of action
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article
Metallosupramolecular assembly of Cr and p-terphenylnitrile by dissociation of metal carbonyls on Au(111)
Abstract
Metal carbonyl complexes have been widely investigated for use in heterogeneous catalysis as a method for the formation of metal clusters. However their use as a metal source for metallosupramolecular assemblies has not been widely considered. In this study, the combination of Cr(CO)6 with p-terphenylnitrile on Au(111) creates ordered 1D chains which are thermally stable up to 473 K. The bond between the nitrile linkers and metal nodes undergoes a unique π-interaction which thus far has been observed only in a small set of organometallic complexes in solution. The structure and composition of the metal organic coordination network have been elucidated and characterized using scanning tunnelling microscopy, high resolution electron energy loss spectroscopy and density functional theory calculations.