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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Baddeley, Christopher John
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Understanding the passivation layer formed by tolyltriazole on copper, bronze, and brass surfaces
- 2022Highly ordered N-heterocyclic carbene monolayers on Cu(111)citations
- 2022Surface confined hydrogenation of graphene nanoribbonscitations
- 2022Adsorption of the prototypical organic corrosion inhibitor benzotriazole on the Cu(100) surfacecitations
- 2016Metallosupramolecular assembly of Cr and p-terphenylnitrile by dissociation of metal carbonyls on Au(111)citations
- 2006The growth of ultrathin Au films on Ni{1 1 1}citations
- 2004An investigation of the adsorption of (R,R)-tartaric acid on oxidised Ni{1 1 1} surfacescitations
- 2003Structural and compositional analysis of two near-surface alloys produced by adsorption and thermal decomposition of Mo(CO) 6 on Ni{111)citations
Places of action
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article
Metallosupramolecular assembly of Cr and p-terphenylnitrile by dissociation of metal carbonyls on Au(111)
Abstract
Metal carbonyl complexes have been widely investigated for use in heterogeneous catalysis as a method for the formation of metal clusters. However their use as a metal source for metallosupramolecular assemblies has not been widely considered. In this study, the combination of Cr(CO)6 with p-terphenylnitrile on Au(111) creates ordered 1D chains which are thermally stable up to 473 K. The bond between the nitrile linkers and metal nodes undergoes a unique π-interaction which thus far has been observed only in a small set of organometallic complexes in solution. The structure and composition of the metal organic coordination network have been elucidated and characterized using scanning tunnelling microscopy, high resolution electron energy loss spectroscopy and density functional theory calculations.