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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Fruchtl, Herbert Anton
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023Electrochemical activation applied to perovskite titanate fibres to yield supported alloy nanoparticles for electrocatalytic applicationcitations
- 2022Highly ordered N-heterocyclic carbene monolayers on Cu(111)citations
- 2019Calculating the frequencies and intensities of strongly anharmonic modes of adsorbates on surfacescitations
- 2016Metallosupramolecular assembly of Cr and p-terphenylnitrile by dissociation of metal carbonyls on Au(111)citations
- 2014Coupling Epitaxy, Chemical Bonding, and Work Function at the Local Scale in Transition Metal-Supported Graphenecitations
- 2014Passivation of Copper: Benzotriazole Films on Cu (111)citations
- 2012An ordered organic radical adsorbed on a Cu-doped Au(111) surfacecitations
- 2010Coupling Epitaxy, Chemical Bonding, and Work Function at the Local Scale in Transition Metal-Supported Graphenecitations
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article
Metallosupramolecular assembly of Cr and p-terphenylnitrile by dissociation of metal carbonyls on Au(111)
Abstract
Metal carbonyl complexes have been widely investigated for use in heterogeneous catalysis as a method for the formation of metal clusters. However their use as a metal source for metallosupramolecular assemblies has not been widely considered. In this study, the combination of Cr(CO)6 with p-terphenylnitrile on Au(111) creates ordered 1D chains which are thermally stable up to 473 K. The bond between the nitrile linkers and metal nodes undergoes a unique π-interaction which thus far has been observed only in a small set of organometallic complexes in solution. The structure and composition of the metal organic coordination network have been elucidated and characterized using scanning tunnelling microscopy, high resolution electron energy loss spectroscopy and density functional theory calculations.