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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Roeffaers, Maarten
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Topics
Publications (7/7 displayed)
- 2024Investigation of the Octahedral Network Structure in Formamidinium Lead Bromide Nanocrystals by Low-Dose Scanning Transmission Electron Microscopycitations
- 2023Temperature-Dependent Evolution of the Structural and Optoelectronic Properties of (NH 4 ) 3 Sb 2 I 9 Single Crystals
- 2023Temperature-Dependent Evolution of the Structural and Optoelectronic Properties of (NH4)3Sb2I9 Single Crystals
- 2022Local structure mapping of gel-spun ultrahigh-molecular-weight polyethylene fiberscitations
- 2022An embedded interfacial network stabilizes inorganic CsPbI3 perovskite thin filmscitations
- 2020It's a trap! On the nature of localised states and charge trapping in lead halide perovskitescitations
- 2019Indirect tail states formation by thermal-induced polar fluctuations in halide perovskitescitations
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article
Temperature-Dependent Evolution of the Structural and Optoelectronic Properties of (NH4)3Sb2I9 Single Crystals
Abstract
<p>Hybrid metal halide perovskites are characterized by excellent photoelectric properties with great tunability. By manipulation of their chemical composition, their crystal structure can be altered at the atomic level, leading to confined systems characterized by reduced dimensionality and distinct properties. Here, we provide an in-depth characterization of the structural and optoelectronic properties of 2D (NH<sub>4</sub>)<sub>3</sub>Sb<sub>2</sub>I<sub>9</sub> perovskite single crystals in a wide temperature range (4.2-300 K). Upon cooling, changes in the material’s thermal expansion led to a strong increase in the photoluminescence (PL) intensity. Our findings define the underlying photophysics of this system and the structure-property relationships, thereby paving the way for the optimization and rational design of optoelectronic applications.</p>