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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Alabarse, Frederico
Elettra-Sincrotrone Trieste S.C.p.A.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Structural stability and adsorption behaviour of CO2-loaded pure silica CHA and ITW zeolites upon compressioncitations
- 2022Compressibility, Phase Transition, and Argon Insertion in the Siliceous Zeolite Mobil-Twelve at High Pressurecitations
- 2021High-Pressure Synthesis and Gas-Sensing Tests of 1-D Polymer/Aluminophosphate Nanocompositescitations
- 2021High-Pressure Synthesis and Gas-Sensing Tests of 1-D Polymer/Aluminophosphate Nanocompositescitations
- 2020Single-crystal diffraction at the high-pressure Indo-Italian beamline Xpress at Elettra, Triestecitations
- 2019Effect of H2O on the Pressure-Induced Amorphization of Hydrated AlPO4-17citations
- 2019Effect of H2O on the Pressure-Induced Amorphization of Hydrated AlPO4-17citations
- 2017Anomalous Compressibility and Amorphization in AlPO4-17, the Oxide with the Highest Negative Thermal Expansioncitations
- 2015AlPO4-54-AlPO4-8 Structural Phase Transition and Amorphization under High Pressurecitations
- 2014New experimental set-ups for studying nanoconfined water on the AILES beamline at SOLEILcitations
- 2014Effect of H2O on the Pressure-Induced Amorphization of AlPO4-54 center dot xH(2)Ocitations
Places of action
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article
Compressibility, Phase Transition, and Argon Insertion in the Siliceous Zeolite Mobil-Twelve at High Pressure
Abstract
The siliceous zeolite Socony Mobil-twelve (ZSM-12) or MTW (Mobil-TWelve) with a one-dimensional pore system was studied at high pressure by synchrotron X-ray powder diffraction in nonpenetrating DAPHNE7474 oil and in a penetrating argon pressure medium. A phase transition from the space group C2/c to P2/n is observed in the nonpenetrating medium at close to 1.5 GPa with a 4% volume decrease and a strong increase in compressibility in the ac plane corresponding to partial collapse of the pores. Strong decreases in diffracted intensity are observed with further compression, and the diffraction pattern contains broad features characteristic of an amorphous material above 10 GPa. Distinct behavior is observed when this material is pressurized in argon. Argon fills the pores with 9 ± 1 Ar atoms per unit cell. In this medium-pore zeolite, the quantity of inserted argon was not found to vary with pressure. Argon-filled MTW is 35% less compressible than the corresponding empty form