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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hermet, Patrick
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Insights into the need for ab-initio calculations to accurately predict the optical properties of metallic carbon nanotubes based on experimental confrontation
- 2023Interplay between H-bonding proton dynamics and Fe valence fluctuations in Fe 3 ( P O 4 ) 2 ( OH ) 2 at high pressure
- 2022Compressibility, Phase Transition, and Argon Insertion in the Siliceous Zeolite Mobil-Twelve at High Pressurecitations
- 2020Influence of Nanostructuration on the Vibrational, Electronic and Optical Properties of CrSi 2 Thin Filmscitations
- 2020Influence of Nanostructuration on the Vibrational, Electronic and Optical Properties of CrSi<sub>2</sub> Thin Filmscitations
- 2019High-pressure, high temperature insertion of bismuth in the siliceous zeolite silicalite-1citations
- 2017Supramolecular organization of a H-bonded perylene bisimide organogelator determined by transmission electron microscopy, grazing incidence X-ray diffraction and polarized infra-red spectroscopycitations
- 2017Supramolecular organization of a H-bonded perylene bisimide organogelator determined by transmission electron microscopy, grazing incidence X-ray diffraction and polarized infra-red spectroscopycitations
- 2017Experimental and first-principles calculation study of the pressure-induced transitions to a metastable phase in GaPO4 and in the solid solution AlPO4-GaPO4citations
- 2017Experimental and first-principles calculation study of the pressure-induced transitions to a metastable phase in GaPO4 and in the solid solution AlPO4-GaPO4citations
- 2014Linear electro-optic effect in multiferroic BiFeO3 thin filmscitations
- 2014First-principles characterization of the P21ab ferroelectric phase of Aurivillius Bi2WO6citations
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article
Compressibility, Phase Transition, and Argon Insertion in the Siliceous Zeolite Mobil-Twelve at High Pressure
Abstract
The siliceous zeolite Socony Mobil-twelve (ZSM-12) or MTW (Mobil-TWelve) with a one-dimensional pore system was studied at high pressure by synchrotron X-ray powder diffraction in nonpenetrating DAPHNE7474 oil and in a penetrating argon pressure medium. A phase transition from the space group C2/c to P2/n is observed in the nonpenetrating medium at close to 1.5 GPa with a 4% volume decrease and a strong increase in compressibility in the ac plane corresponding to partial collapse of the pores. Strong decreases in diffracted intensity are observed with further compression, and the diffraction pattern contains broad features characteristic of an amorphous material above 10 GPa. Distinct behavior is observed when this material is pressurized in argon. Argon fills the pores with 9 ± 1 Ar atoms per unit cell. In this medium-pore zeolite, the quantity of inserted argon was not found to vary with pressure. Argon-filled MTW is 35% less compressible than the corresponding empty form