• Jones, Michael A.
• Goor, Tim W. J. Van De
• Liu, Yun
• Kelly, Nicola D.
• Emge, Steffen P.
• Liu, Cheng
• Neumann, Timo
• Monserrat, Bartomeu
• Bourelle, Sean A.
• Feldmann, Sascha
• Deschler, Felix
• Winkler, Thomas
• Friend, Richard H.
• Dutton, Siân E.

Abstract

<p>Band gap tuning of hybrid metal-halide perovskites by halide substitution holds promise for tailored light absorption in tandem solar cells and emission in light-emitting diodes. However, the impact of halide substitution on the crystal structure and the fundamental mechanism of photo-induced halide segregation remain open questions. Here, using a combination of temperature-dependent X-ray diffraction and calorimetry measurements, we report the emergence of a disorder- and frustration-driven orientational glass for a wide range of compositions in CH3NH3Pb(ClxBr1-x)3. Using temperature-dependent photoluminescence measurements, we find a correlation between halide segregation under illumination and local strains from the orientational glass. We observe no glassy behavior in CsPb(ClxBr1-x)3, highlighting the importance of the A-site cation for the structure and optoelectronic properties. Using first-principles calculations, we identify the local preferential alignment of the organic cations as the glass formation mechanism. Our findings rationalize the superior photostability of mixed-cation metal-halide perovskites and provide guidelines for further stabilization strategies. </p>

Topics

• perovskite
• photoluminescence
• x-ray diffraction
• glass
• glass
• calorimetry