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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Baranov, Dmitry
Lund University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Exogenous Metal Cations in the Synthesis of CsPbBr3 Nanocrystals and Their Interplay with Tertiary Aminescitations
- 2024Exogenous Metal Cations in the Synthesis of CsPbBr3 Nanocrystals and Their Interplay with Tertiary Aminescitations
- 2023Collective Diffraction Effects in Perovskite Nanocrystal Superlatticescitations
- 2022Exploiting the Transformative Features of Metal Halides for the Synthesis of CsPbBr3@SiO2 Core-Shell Nanocrystalscitations
- 2022Highly Emitting Perovskite Nanocrystals with 2-Year Stability in Water through an Automated Polymer Encapsulation for Bioimagingcitations
- 2021Detection of Pb2+traces in dispersion of Cs4PbBr6 nanocrystals by in situ liquid cell transmission electron microscopycitations
- 2021Structure and Surface Passivation of Ultrathin Cesium Lead Halide Nanoplatelets Revealed by Multilayer Diffractioncitations
- 2021Metamorphoses of Cesium Lead Halide Nanocrystalscitations
- 2021Exploiting the Transformative Features of Metal Halides for the Synthesis of CsPbBr3@SiO2 Core–Shell Nanocrystalscitations
- 2020Superlattices are greener on the other sidecitations
- 2020Transforming colloidal Cs4PbBr6 nanocrystals with poly(maleic anhydride-alt-1-octadecene) into stable CsPbBr3 perovskite emitters through intermediate heterostructurescitations
- 2020Cs 3 Cu 4 In 2 Cl 13 Nanocrystals:A Perovskite-Related Structure with Inorganic Clusters at A Sitescitations
- 2020Cs3Cu4In2Cl13 Nanocrystalscitations
- 2019Purification of Oleylamine for Materials Synthesis and Spectroscopic Diagnostics for trans Isomerscitations
- 2019Fully Inorganic Ruddlesden-Popper Double Cl-I and Triple Cl-Br-I Lead Halide Perovskite Nanocrystalscitations
- 2018Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystalscitations
- 2018Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystalscitations
- 2007Synthesis of cerium oxide nanoparticles in polyethylene matrixcitations
- 2006Optical properties of cadmium sulfide nanoparticles on the surface of polytetrafluoroethylene nanogranulescitations
- 2006Cobalt-containing core-shell nanoparticles on the surface of poly(tetrafluoroethylene) microgranulescitations
- 2006Copper nanoparticles on the surface of ultradispersed polytetrafluoroethylene nanograinscitations
- 2006New magnetic materials based on cobalt and iron-containing nanopariclescitations
- 2005Synthesis and structure of polyethylene-matrix composites containing zinc oxide nanoparticlescitations
Places of action
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article
Cs3Cu4In2Cl13 Nanocrystals
Abstract
<p>An effort to synthesize the Cu(I) variant of a lead-free double perovskite isostructural with Cs<sub>2</sub>AgInCl<sub>6</sub> resulted in the formation of Cs<sub>3</sub>Cu<sub>4</sub>In<sub>2</sub>Cl<sub>13</sub> nanocrystals with an unusual structure, as revealed by single-nanocrystal three-dimensional electron diffraction. These nanocrystals adopt a A<sub>2</sub>BX<sub>6</sub> structure (K<sub>2</sub>PtCl<sub>6</sub> type, termed vacancy ordered perovskite) with tetrahedrally coordinated Cu(I) ions. In the structure, 25% of the A sites are occupied by [Cu<sub>4</sub>Cl]<sup>3+</sup> clusters (75% by Cs<sup>+</sup>), and the B sites are occupied by In<sup>3+</sup>. Such a Cs<sub>3</sub>Cu<sub>4</sub>In<sub>2</sub>Cl<sub>13</sub> compound prepared at the nanoscale is not known in the bulk and is an example of a multinary metal halide with inorganic cluster cations residing in A sites. The stability of the compound was supported by density functional theory calculations that also revealed that its bandgap is direct but parity forbidden. The existence of the Cs<sub>3</sub>Cu<sub>4</sub>In<sub>2</sub>Cl<sub>13</sub> structure demonstrates that small inorganic cluster cations can occupy A sites in multinary metal halides.</p>