| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mcinnes, Eric J. L.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Metal-carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopycitations
- 2024Two‐ and Three‐Spin Hybrid Inorganic‐Organic [2]Rotaxanes Containing Metallated Salen Groups
- 2021High Ammonia Adsorption in MFM-300 Materials:Dynamics and Charge Transfer in Host–Guest Bindingcitations
- 2021Catalytic decomposition of NO 2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021High Ammonia Adsorption in MFM-300 Materialscitations
- 2021Catalytic decomposition of NO2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021Catalytic decomposition of NO2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2020Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal-Organic Frameworkscitations
- 2020Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal-Organic Frameworkscitations
- 2019Iodine adsorption in a redox-active metal-organic frameworkcitations
- 2016Emergence of comparable covalency in isostructural cerium(IV)- and uranium(IV)-carbon multiple bondscitations
- 2015Copper Lanthanide Phosphonate Cages: Highly Symmetric {Cu(3)Ln(9)P(6)} and {Cu(6)Ln(6)P(6)} Clusters with C-3v and D-3h Symmetrycitations
- 2007Tuning intermolecular magnetic exchange interactions in the solids C xF2x(CNSSS)2(AsF6)2: Structural, EPR, and magnetic characterization of dimeric (x = 2, 4) diradicalscitations
- 2006Incorporation of fused tetrathiafulvalenes (TTFs) into polythiophene architectures: Varying the electroactive dominance of the TTF species in hybrid systemscitations
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article
Iodine adsorption in a redox-active metal-organic framework
Abstract
We report a comparative study of the binding of I2 (iodine) in a pair of redox-active metal-organic framework (MOF) materials, MFM-300(VIII) and its oxidized, deprotonated analogue, MFM-300(VIV). Adsorption of I2 in MFM-300(VIII) triggers a host-to-guest charge transfer, accompanied by a partial (~30%) oxidation of the VIII centres in the host framework and formation of I3- species residing in the MOF channels. Importantly, this charge transfer induces a significant enhancement in the electrical conductivity (Δσ = 700,000) of I2@MFM-300(VIII/IV) in comparison to MFM-300(VIII). In contrast, no host-guest charge-transfer or apparent change in conductivity was observed on adsorption of I2 in MFM-300(VIV). High resolution synchrotron X-ray diffraction of I2@MFM-300(VIII/IV) confirms the first example of self-aggregation of adsorbed iodine species (I2 and I3-) into infinite helical chains within a MOF. <br/>