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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Blake, Alexander
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2023Organoruthenium Complexes Containing Phosphinodicarboxamide Ligands
- 2018High Volumetric Hydrogen Adsorption in a Porous Anthracene-decorated Metal–Organic Frameworkcitations
- 2018High Volumetric Hydrogen Adsorption in a Porous Anthracene-decorated Metal–Organic Frameworkcitations
- 2016Emergence of comparable covalency in isostructural cerium(IV)– and uranium(IV)–carbon multiple bonds
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article
High Volumetric Hydrogen Adsorption in a Porous Anthracene-decorated Metal–Organic Framework
Abstract
<p>We report an unprecedented ligand-based binding domain for D<sub>2</sub> within a porous metal-organic framework (MOF) material as confirmed by neutron powder diffraction studies of D<sub>2</sub> -loaded MFM-132a. A tight pocket of 6 Å diameter is formed by the close packing of three anthracene panels, and it is here rather than the open metal sites where D<sub>2</sub> binds preferentially. As a result, MFM-132a shows exceptional volumetric hydrogen adsorption (52 g L<sup>-1</sup> at 60 bar and 77 K) and the highest density of adsorbed H<sub>2</sub> within its pores among all the porous materials reported to date under the same conditions. This work points to a new direction for H<sub>2</sub> storage in porous materials using polyaromatic ligand-based sites.</p>