693.932 PEOPLE
| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Yang, Sihai
University of Manchester
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (32/32 displayed)
- 2024Electron Beam and Thermal Stabilities of MFM-300(M) Metal-Organic Frameworkscitations
- 2024Hierarchical porous metal-organic polyhedra for efficient oxidative cleavage of β-O-4 bonds in lignin model compound
- 2022Adsorption of sulphur dioxide in Cu(II)-carboxylate framework materials: the role of ligand functionalisation and open metal sites
- 2022Direct visualisation of supramolecular binding and separation of light hydrocarbons in MFM-300(In)
- 2022How reproducible are surface areas calculated from the BET equation?citations
- 2022How reproducible are surface areas calculated from the BET equation?citations
- 2022How Reproducible are Surface Areas Calculated from the BET Equation?citations
- 2022How Reproducible are Surface Areas Calculated from the BET Equation?citations
- 2021High Ammonia Adsorption in MFM-300 Materials:Dynamics and Charge Transfer in Host–Guest Bindingcitations
- 2021Catalytic decomposition of NO 2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021High Ammonia Adsorption in MFM-300 Materialscitations
- 2021How Reproducible Are Surface Areas Calculated from the BET Equation?citations
- 2021Catalytic decomposition of NO2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021Catalytic decomposition of NO2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021Atomically-dispersed copper sites in a metal-organic framework for reduction of nitrogen dioxide
- 2021Simultaneous Neutron Powder Diffraction and Microwave Characterisation at Elevated Temperatures
- 2020Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal-Organic Frameworkscitations
- 2020Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal-Organic Frameworkscitations
- 2019Iodine adsorption in a redox-active metal-organic frameworkcitations
- 2019Iodine adsorption in a redox-active metal-organic framework:Electrical conductivity induced by host-guest charge-transfercitations
- 2018Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Frameworkcitations
- 2018Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Frameworkcitations
- 2018High Volumetric Hydrogen Adsorption in a Porous Anthracene-decorated Metal–Organic Frameworkcitations
- 2018High Volumetric Hydrogen Adsorption in a Porous Anthracene-decorated Metal–Organic Frameworkcitations
- 2018Enhancement of CO2 uptake and selectivity in a metal-organic framework by incorporation of thiophene functionalitycitations
- 2017Porous metal–organic polyhedral frameworks with optimal molecular dynamics and pore geometry for methane storagecitations
- 2017Stepwise Observation and Quantification and Mixed Matrix Membrane Separation of CO2 within a Hydroxy-Decorated Porous Hostcitations
- 2017Porous Metal–Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storagecitations
- 2016Enhancement of CO2 Adsorption and Catalytic Properties by Fe-Doping of [Ga-2(OH)(2)(L)] (H4L = Biphenyl-3,3 ',5,5 '-tetracarboxylic Acid), MFM-300(Ga-2)citations
- 2014Inelastic neutron scattering study of binding of para-hydrogen in an ultra-microporous metal–organic frameworkcitations
- 2014A Novel Bismuth-Based Metal-Organic Framework for High Volumetric Methane and Carbon Dioxide Adsorptioncitations
- 2010Metal-Organic Polyhedral Frameworks: High H-2 Adsorption Capacities and Neutron Powder Diffraction Studies
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article
High Volumetric Hydrogen Adsorption in a Porous Anthracene-decorated Metal–Organic Framework
Abstract
<p>We report an unprecedented ligand-based binding domain for D<sub>2</sub> within a porous metal-organic framework (MOF) material as confirmed by neutron powder diffraction studies of D<sub>2</sub> -loaded MFM-132a. A tight pocket of 6 Å diameter is formed by the close packing of three anthracene panels, and it is here rather than the open metal sites where D<sub>2</sub> binds preferentially. As a result, MFM-132a shows exceptional volumetric hydrogen adsorption (52 g L<sup>-1</sup> at 60 bar and 77 K) and the highest density of adsorbed H<sub>2</sub> within its pores among all the porous materials reported to date under the same conditions. This work points to a new direction for H<sub>2</sub> storage in porous materials using polyaromatic ligand-based sites.</p>