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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Dudziec, Beata
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Preparation of T8 and double-decker silsesquioxane-based Janus-type molecules: molecular modeling and DFT insights
- 2024Crystallization behavior and thermal properties of octa-phenyl-substituted silsesquioxane-modified polylactide (PLA)citations
- 2023Metallodendrimers Unveiled: Investigating the Formation and Features of Double-Decker Silsesquioxane-Based Silylferrocene Dendrimerscitations
- 2022Slick Synthetic Approach to Various Fluoroalkyl Silsesquioxanes—Assessment of their Dielectric Propertiescitations
- 2019Synthetic routes to silsesquioxane-based systems as photoactive materials and their precursorscitations
- 2018Multi-alkenylsilsesquioxanes as comonomers and active species modifiers of metallocene catalyst in copolymerization with ethylenecitations
- 2018Interfacial interactions in PTT–PTMO/polyhedral oligomeric silsesquioxane (POSS) nanocomposites and their impact on mechanical, thermal, and dielectric propertiescitations
- 2017Copolymers of ethylene with monoalkenyl- and monoalkenyl(siloxy)silsesquioxane (POSS) comonomers – Synthesis and characterizationcitations
- 2017Evaluation of thermomechanical properties of epoxy–basalt fibre composites modified with zeolite and silsesquioxanecitations
- 2016Morphology, mechanical properties and processability of poly(ethylene terephthalate) modified by polyhedral oligomeric silsesquioxanes
- 2015Morphology and phase separation in PTT-block-PTMO nanocomposites containing POSS particlescitations
- 2014Influence of a sorbitol-based nucleating agent modified with silsesquioxanes on the non-isothermal crystallization of isotactic polypropylenecitations
- 2014Thermal Stability and Flammability of Polypropylene-Silsesquioxane Nanocompositescitations
- 2013Processing properties of thermoplastic polymers modified by polyhedral oligomeric silsesquioxanes (POSS)citations
Places of action
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article
Metallodendrimers Unveiled: Investigating the Formation and Features of Double-Decker Silsesquioxane-Based Silylferrocene Dendrimers
Abstract
Dendrimers exhibiting reversible redox properties have attracted extensive attention for their potential as electron transfer mediators, catalysts, and molecular sensors. In this study, we introduce intriguing G1 and G2 dendrimers featuring double-decker silsesquioxane cores and silylferrocene moieties. Through a carefully orchestrated sequence of condensation, reduction, and hydrosilylation reactions, these compounds were synthesized and comprehensively characterized spectroscopically and spectrometrically. Our investigation also encompassed the examination of their properties, including thermal stability, solubility in common organic solvents, and electrochemical behavior. We determined that these dendrimers possess the capability to form monolayers on platinum electrodes, which we conclusively demonstrated through the probing of cyclic voltammetry, electrochemical impedance spectroscopy, and scanning electron microscopy imaging. Notably, this study marks the first-ever example of modifying double-decker silsesquioxane cores with ferrocene groups while simultaneously representing one of the scarce instances of dendrimers exhibiting an open double-decker silsesquioxane core.