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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mahon, Mary F.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Dial-a-base mechanochemical synthesis of N-heterocyclic carbene copper complexescitations
- 2023Alkali Metal Reduction of Alkali Metal Cationscitations
- 2023The Complex Reactivity of [(salen)Fe]2(μ-O) with HBpin and its Implications in Catalysiscitations
- 2022Coupling Postsynthetic High-Temperature Oxidative Thermolysis and Thermal Rearrangements in Isoreticular Zinc MOFscitations
- 2022Coupling Postsynthetic High-Temperature Oxidative Thermolysis and Thermal Rearrangements in Isoreticular Zinc MOFscitations
- 2017Deposition of SnS Thin Films from Sn(II) Thioamidate Precursorscitations
- 2016Aminopiperidine based complexes for lactide polymerisationcitations
- 2016Homoleptic zirconium amidatescitations
- 2015The synthesis and characterisation of coordination and hydrogen-bonded networks based on 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoic acidcitations
- 2011Homopiperazine and piperazine complexes of Zr(IV) and Hf(IV) and their application to the ring-opening polymerisation of lactidecitations
- 2011Salalen aluminium complexes and their exploitation for the ring opening polymerisation of rac-lactidecitations
- 2009Effects of microwave radiation on electrode position processes at tin-doped indium oxide (ITO) electrodescitations
- 2009Structural Tungsten-Imido Chemistry: The Gas-Phase Structure of W(NBut)(2)(NHBut)(2) and the Solid-State Structures of Novel Heterobimetallic W/N/M (M = Rh, Pd, Zn) Speciescitations
- 2009Novel Ti(IV) and Zr(IV) complexes and their application in the ring-opening polymerisation of cyclic esterscitations
- 2008Subtle structural variation in copper metal-organic frameworks: Syntheses, structures, magnetic properties and catalytic behaviourcitations
- 2006Incorporation of dyes into hydrogen-bond networks: The structures and properties of guanidinium sulfonate derivatives containing ethyl orange and 4-aminoazobenzene-4 '-sulfonate
- 2006Synthesis and X-ray structures of new titanium(IV) aryloxides and their exploitation for the ring opening polymerization of epsilon-caprolactonecitations
- 2005A new polymorph of terpyridine: variable temperature X-ray diffraction studies and solid state photophysical propertiescitations
- 2003exo-closo-rhodacarboranes: synthesis and characterisation of [{exo-(R3P)(2)Rh}(closo-CB11H12)][R3P = P(OMe)(3), PCy3, 1/2dppe]citations
- 2003The influence of functional group orientation on the structure of zinc 1,1,4-trimethylthiosemicarbazide dicarboxylates: Probing the limits of crystal engineering strategies
- 2003Synthesis, characterisation and optical spectroscopy of diynes and poly-ynes containing derivatised fluorenes in the backbonecitations
- 2002Structural characterisation of a series of acetylide-functionalised oligopyridines and the synthesis, characterisation and optical spectroscopy of platinum di-ynes and poly-ynes containing oligopyridyl linker groups in the backbonecitations
Places of action
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article
Coupling Postsynthetic High-Temperature Oxidative Thermolysis and Thermal Rearrangements in Isoreticular Zinc MOFs
Abstract
<p>Herein, we report coupling in situ high temperature postsynthetic modifications (PSMs) in metal–organic frameworks (MOFs). Thermo-reactive propargyloxy-functionalized zinc IRMOFs (isoreticular metal–organic frameworks) prepared from 2-(prop-2-yn-1-yloxy)-[1,1′-biphenyl]-4,4′-dicarboxylic acid (H<sub>2</sub>bpdcOCH<sub>2</sub>CCH) were investigated for their high-temperature postsynthetic rearrangement (PSR) chemistry to heterocyclic chromenes and benzofurans and then coupled to solid–gas reactions with molecular oxygen. The selectivity for the initial molecular rearrangements was found to be inverted in the porous MOF environment compared to conventional melt reactions of the ester compound Me<sub>2</sub>bpdcOCH<sub>2</sub>CCH and proceeded far more easily than the solid-state transformation from H<sub>2</sub>bpdcOCH<sub>2</sub>CCH, showing the potential of MOFs to give rise to different chemistry. The major oxidative process was thermolysis of the chromene ring with a minor pathway of allylic-type oxidation to give heterocyclic chromenone functionality. The sequence was also successful on a series of two-component multivariate IRMOF frameworks prepared from thermo-reactive H<sub>2</sub>bpdcOCH<sub>2</sub>CCH and thermo-resistant H<sub>2</sub>bpdcOMe linkers, demonstrating that these reactions can be used with known crystal engineering strategies. All transformations were fully compatible with the requirements to maintain MOF crystallinity and porosity as evidenced by surface area analysis and X-ray powder diffraction measurements. This work contributes to establishing the feasibility of high-temperature solid–gas manifolds for MOF PSM.</p>