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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Bernot, Kevin
Institut National des Sciences Appliquées de Rennes
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Halogen-Bonds-Based Strategy for the Design of Highly Luminescent Lanthanide Coordination Polymers as Taggants for Plastic Waste Sortingcitations
- 2023Metallogels: a novel approach for the nanostructuration of single-chain magnetscitations
- 2022Investigation of Intermetallic Energy Transfers in Lanthanide Coordination Polymers Molecular Alloys: Case Study of Trimesate-Based Compoundscitations
- 2022Investigation of Intermetallic Energy Transfers in Lanthanide Coordination Polymers Molecular Alloys: Case Study of Trimesate-Based Compoundscitations
- 2022Synthesis, Crystal Structure, and Luminescence Properties of the Iso-Reticular Series of Lanthanide Coordination Polymers Synthesized from Hexa-Lanthanide Molecular Precursorscitations
- 2022Microwave-assisted synthesis of lanthanide coordination polymers with 2-bromobenzoic acid as ligand from hexa-lanthanide molecular precursorscitations
- 2021Highly Luminescent Europium-Based Heteroleptic Coordination Polymers with Phenantroline and Glutarate Ligandscitations
- 2021Hexanuclear Molecular Precursors as Tools to Design Luminescent Coordination Polymers with Lanthanide Segregationcitations
- 2020Luminescence properties of lanthanide complexes-based molecular alloyscitations
- 2020Luminescence properties of lanthanide complexes-based molecular alloyscitations
- 2019Hetero-hexalanthanide Complexes: A New Synthetic Strategy for Molecular Thermometric Probescitations
- 2019A new family of lanthanide-based coordination polymers with azoxybenzene-3,3′,5,5′-tetracarboxylic acid as ligandcitations
- 2019Microcrystalline Core–Shell Lanthanide-Based Coordination Polymers for Unprecedented Luminescent Propertiescitations
- 2018trans to cis photo-isomerization in merocyanine dysprosium and yttrium complexescitations
- 2017Lanthanide coordination polymers with 1,2-phenylenediacetatecitations
- 2017High Brightness and Easy Color Modulation in Lanthanide-Based Coordination Polymers with 5-Methoxyisophthalate as Ligand: Toward Emission Colors Additive Strategycitations
- 2015Extending the lanthanide–terephthalate system: Isolation of an unprecedented Tb(III)-based coordination polymer with high potential porosity and luminescence propertiescitations
- 2014Heteronuclear lanthanide-based coordination polymers exhibiting tunable multiple emission spectracitations
- 2013Synthesis, Crystal Structure and Luminescent Properties of New Lanthanide-Containing Coordination Polymers Involving 4,4'-oxy-bis-benzoate as Ligand.citations
- 2013Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymerscitations
- 2013Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymerscitations
- 2011Lanthanide Aminoisophthalate Coordination Polymers: A Promising System for Tunable Luminescent Propertiescitations
- 2008New lanthanide based coordination polymers with high potential porosity.citations
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article
Hexanuclear Molecular Precursors as Tools to Design Luminescent Coordination Polymers with Lanthanide Segregation
Abstract
Solvothermal reactions between hexanuclear complexes with the general chemical formula [Ln(μ-O)(μ-OH)(NO)(HO)]·2NO·2HO and 2-bromobenzoic acid (2-bbH) lead to a series of isostructural one-dimensional coordination polymers with the general chemical formula [Ln(2-bb)] with Ln = Sm, Eu, Tb, Dy, and Y. These coordination polymers crystallize in the orthorhombic space group 2 (No. 43) with the following cell parameters:= 29.810(3) Å,= 51.185(6) Å,= 11.7913(14) Å,= 17992(4) Å, and= 16. The europium- and terbium-based derivatives show sizable luminescence intensities under UV excitation. Isostructural heterolanthanide coordination polymers have also been prepared. Their luminescent properties suggest that during the synthetic process the starting hexanuclear complexes are destroyed but strongly influence the distribution of the different lanthanide ions over the metallic sites of the crystal structure. Indeed, it is possible to prepare heterolanthanide coordination polymers in which lanthanide-ion segregation is controlled.