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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Murzin, Dmitry Yu
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Interactions between Iron and Nickel in Fe-Ni Nanoparticles on Y Zeolite for Co-Processing of Fossil Feedstock with Lignin-Derived Isoeugenolcitations
- 2023Dry Reforming of Methane over Ni-Fe-Al Catalysts Prepared by Solution Combustion Synthesiscitations
- 2022CuZSM-5@HMS composite as an efficient micro-mesoporous catalyst for conversion of sugars into levulinic acidcitations
- 2022Catalyst supports based on ZnO-ZnAl 2 O 4 nanocomposites with enhanced selectivity and coking resistance in isobutane dehydrogenationcitations
- 2021Effect of metal particle shape on hydrogen assisted reactionscitations
- 2021Mono- and Bimetallic Ni−Co Catalysts in Dry Reforming of Methanecitations
- 2021Mono‐ and Bimetallic Ni−Co Catalysts in Dry Reforming of Methanecitations
- 2020Transformation of industrial steel slag with different structure-modifying agents for synthesis of catalystscitations
- 2019Synthesis and Characterization of Novel Catalytic Materials Using Industrial Slag:Influence of Alkaline Pretreatment, Synthesis Time and Temperaturecitations
- 2019Synthesis and Characterization of Novel Catalytic Materials Using Industrial Slagcitations
- 2016Alumina ceramic foams as catalyst supportscitations
- 2013Imidazolium-Based Poly(ionic liquid)s as New Alternatives for CO2 Capture.citations
- 2010Decarboxylation of fatty acids over Pd supported on mesoporous carboncitations
- 2008Synthesis of biodiesel via deoxygenation of stearic acid over supported Pd/C catalystcitations
Places of action
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article
Dry Reforming of Methane over Ni-Fe-Al Catalysts Prepared by Solution Combustion Synthesis
Abstract
Dry reforming of methane (DRM) is a promising method to utilize two greenhouse gases, such as CH 4 and CO 2 , to produce synthesis gas. In the current work, both monometallic Ni and bimetallic Ni-Fe catalysts with different Fe/Ni molar ratios, synthesized by solution combustion synthesis (SCS) in DRM, were investigated using a feed ratio of CH 4 /CO 2 /Ar of 1:1:1 at 600-900 °C. The catalysts were characterized by several physicochemical techniques such as X-ray diffraction (XRD), scanning electron microscopy energy-dispersive X-ray (SEM-EDX) spectroscopy, transmission electron microscopy (TEM), CHNS, N 2 physisorption, H 2 -TPR, O 2 -TPO, NH 3 -TPD, and thermogravimetric analysis (TGA). One of the highest hydrogen yields of 81% was obtained at 93% conversion of CH 4 and 94% conversion of CO 2 for the bimetallic 15Ni-5Fe-30Al catalyst, which contained, according to XRD, NiAl 2 O 4 spinel and metallic Ni phases. The spinel phase was decomposed during the reaction, while the Ni 3 Fe alloy was formed. Catalysts with a higher Fe/Ni ratio exhibited lower conversion and contained an inactive FeAl 2 O 4 spinel. Rather stable yields of CO and H 2 were obtained in an experiment with 20 h time-on-stream.