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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pichler, Thomas
University of Vienna
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (32/32 displayed)
- 2024Temperature dependence of the Raman spectrum of orthorhombic Bi2Se3
- 2022Highly Sensitive and Selective Formaldehyde Gas Sensors Based on Polyvinylpyrrolidone/Nitrogen-Doped Double-Walled Carbon Nanotubescitations
- 2022Momentum-Dependent Oscillator Strength Crossover of Excitons and Plasmons in Two- Dimensional PtSe2citations
- 2022Momentum-Dependent Oscillator Strength Crossover of Excitons and Plasmons in Two-Dimensional PtSe 2citations
- 2022Molybdenum Release Triggered by Dolomite Dissolutioncitations
- 2021Photothermal synthesis of confined carbynecitations
- 2021In-situ laser annealing as pathway for the metal freesynthesis of tailored nanographenes
- 2021Deciphering the Intense Postgap Absorptions of Monolayer Transition Metal Dichalcogenidescitations
- 2020Ultralong Spin Lifetime in Light Alkali Atom Doped Graphenecitations
- 2019Towards controllable inner chirality in double-walled carbon nanotubescitations
- 2019Metal-Organic Framework Co-MOF-74-Based Host-Guest Composites for Resistive Gas Sensingcitations
- 2019Carbon Nanostructures in Cancer Diagnosis and Therapy
- 2019Position and momentum mapping of vibrations in graphene nanostructurescitations
- 2018Measurement of Optical Excitations in Low-Dimensional Materials by Using a Monochromated Electron Sourcecitations
- 2018Fermi level engineering of metallicity-sorted metallic single-walled carbon nanotubes by encapsulation of few-atom-thick crystals of silver chloridecitations
- 2016Environmental control of electron-phonon coupling in barium doped graphenecitations
- 2016Disentangling Vacancy Oxidation on Metallicity-Sorted Carbon Nanotubescitations
- 2015Atomically precise semiconductor-graphene and hBN interfaces by Ge intercalationcitations
- 2014Raman spectroscopy of graphite intercalation compounds: Charge transfer, strain, and electron–phonon coupling in graphene layerscitations
- 2014Raman spectroscopy of graphite intercalation compoundscitations
- 2014Raman spectroscopy of graphite intercalation compounds ; charge transfer, strain, and electron-phonon coupling in graphene layers
- 2013Manifestation of charged and strained graphene layers in the Raman response of graphite intercalation compounds.citations
- 2013Manifestation of Charged and Strained Graphene Layers in the Raman Response of Graphite Intercalation Compoundscitations
- 2013Hybrid Carbon Nanotube Networks as Efficient Hole Extraction Layers for Organic Photovoltaicscitations
- 2011Nitrogen-Doped Single-Walled Carbon Nanotube Thin Films Exhibiting Anomalous Sheet Resistancescitations
- 2011Nanochemical reactions by laser annealing of ferrocene filled single-walled carbon nanotubescitations
- 2010Evidence for substitutional boron in doped single-walled carbon nanotubescitations
- 2009Carbon nanotube synthesis via ceramic catalystscitations
- 2008Tight-binding description of the quasiparticle dispersion of graphite and few-layer graphenecitations
- 2008A one step approach to B-doped single-walled carbon nanotubescitations
- 2006High quality double wall carbon nanotubes with a defined diameter distribution by chemical vapor deposition from alcoholcitations
- 2004Low temperature fullerene encapsulation in single wall carbon nanotubes: Synthesis of N@C60@SWCNTcitations
Places of action
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article
Molybdenum Release Triggered by Dolomite Dissolution
Abstract
The injection of oxygenated water into anoxic aquifers during managed aquifer recharge (MAR) can cause the mobilization of metal(loid)s. Here, we study the processes controlling MAR-induced molybdenum (Mo) release in dolomitic aquifers. Sequential chemical extractions and energy dispersive X-ray spectroscopy combined with scanning electron microscopy point to an association of Mo with easily soluble sulfurized organic matter present in intercrystalline spaces of dolomites or directly incorporated within dolomite crystals. The easily soluble character was confirmed by a batch experiment that demonstrated the rapid mobilization of Mo, dissolved organic carbon, and sulfur. The type and time of batch solution contact with the sulfurized organic matter impacted the release of Mo, as demonstrated by a 36% increase in Mo concentrations when shaking was intensified. Based on the experimental results, a conceptual model for the release of Mo was formulated, where (i) the injection of oxygenated water causes the oxidation of pyrite in the aquifer matrix, and (ii) the associated release of protons (H+) induces the dissolution of dolomite as a buffering reaction, which (iii) enhances the accessibility of the injectant to intercrystalline and incorporated sulfurized organic matter within dolomite, causing the release of Mo.