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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Okoro, Sunday Chukwudi
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Topics
Publications (24/24 displayed)
- 2018Time and temperature effects on alkali chloride induced high temperature corrosion of superheaters during biomass firingcitations
- 2018Time and temperature effects on alkali chloride induced high temperature corrosion of superheaters during biomass firingcitations
- 2018Influence of Preoxidation on High-Temperature Corrosion of a FeCrAl Alloy Under Conditions Relevant to Biomass Firingcitations
- 2017Influence of preoxidation on high temperature corrosion of a Ni-based alloy under conditions relevant to biomass firingcitations
- 2017Influence of preoxidation on high temperature corrosion of a Ni-based alloy under conditions relevant to biomass firingcitations
- 2017Complementary Methods for the Characterization of Corrosion Products on a Plant-Exposed Superheater Tubecitations
- 2017Complementary Methods for the Characterization of Corrosion Products on a Plant-Exposed Superheater Tubecitations
- 2017Effect of flue gas composition on deposit induced high temperature corrosion under laboratory conditions mimicking biomass firing. Part I: Exposures in oxidizing and chlorinating atmospherescitations
- 2017Effect of flue gas composition on deposit induced high temperature corrosion under laboratory conditions mimicking biomass firing. Part I: Exposures in oxidizing and chlorinating atmospherescitations
- 2017Effect of flue gas composition on deposit induced high temperature corrosion under laboratory conditions mimicking biomass firing. Part II: Exposures in SO 2 containing atmospherescitations
- 2017Effect of flue gas composition on deposit induced high temperature corrosion under laboratory conditions mimicking biomass firing. Part II: Exposures in SO2 containing atmospherescitations
- 2016High Temperature Corrosion on Biodust Firing
- 2016Laboratory Investigations of Ni-Al Coatings Exposed to Conditions Simulating Biomass Firing
- 2016Laboratory Investigations of Ni-Al Coatings Exposed to Conditions Simulating Biomass Firing
- 2015Effect of Water Vapor on High-Temperature Corrosion under Conditions Mimicking Biomass Firingcitations
- 2015Effect of Water Vapor on High-Temperature Corrosion under Conditions Mimicking Biomass Firingcitations
- 2015High temperature corrosion during biomass firing: improved understanding by depth resolved characterisation of corrosion productscitations
- 2015High temperature corrosion during biomass firing: improved understanding by depth resolved characterisation of corrosion productscitations
- 2015Alkali chloride induced corrosion of superheaters under biomass firing conditions: Improved insights from laboratory scale studies
- 2015Alkali chloride induced corrosion of superheaters under biomass firing conditions: Improved insights from laboratory scale studies
- 2014High Temperature Corrosion under Laboratory Conditions Simulating Biomass-Firing: A Comprehensive Characterization of Corrosion Productscitations
- 2014High Temperature Corrosion under Laboratory Conditions Simulating Biomass-Firing: A Comprehensive Characterization of Corrosion Productscitations
- 2014High temperature corrosion under conditions simulating biomass firing: depth-resolved phase identification
- 2014High temperature corrosion under conditions simulating biomass firing: depth-resolved phase identification
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article
Time and temperature effects on alkali chloride induced high temperature corrosion of superheaters during biomass firing
Abstract
The high content of alkali chloride in deposits which form during biomass firing in power plants contributes significantly to corrosion of the superheaters. In order to understand the influence of time and temperature on high temperature corrosion under such harsh conditions, laboratory scale studies as a function of time and temperature were carried out using KCl coated samples of the austenitic stainless steel (TP347H). To understand the progress of corrosion with time, isothermal exposures at 560 oC (from 83.5 h to 672 h), and at 600 oC (from 83.5 h to 168 h) were conducted in a gas mixture comprising of O<sub>2</sub>, H<sub>2</sub>O, CO<sub>2</sub>, HCl and SO<sub>2</sub>. In addition, samples were subjected to temperature variations between 560 oC and 600 oC to gain insights on the influence of temperature. The microstructure and elemental composition of the corrosion products resulting from the exposures were studied with scanning electron microscopy and energy dispersive X-ray spectroscopy, respectively. The results show that corrosion attack progressed with time such that the thickness of the consistently identified three regions of corrosion products increased with time, therefore suggesting that the corrosion products were not protective. Also, exposures under varying temperature conditions revealed that an increased corrosion attack would always occur once the superheater experiences a higher temperature, because, a memory effect from prior exposure at higher temperature propagates more corrosion attack during subsequent exposure to a lower temperature.