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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wu, Hao
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2023Investigating the Interaction between Ilmenite and Zinc for Chemical Loopingcitations
- 2023Full-scale investigations of initial deposits formation in a cement plant co-fired with coal and SRFcitations
- 2022Powder Reuse in Laser-Based Powder Bed Fusion of Ti6Al4V—Changes in Mechanical Properties during a Powder Top-Up Regimecitations
- 2022On the application of Vickers micro hardness testing to isotactic polypropylenecitations
- 2022Thermal Conversion of Sodium Phytate Using the Oxygen Carrier Ilmenite Interaction with Na-Phosphate and Its Effect on Reactivitycitations
- 2021Analysis of spatter removal by sieving during a powder-bed fusion manufacturing campaign in grade 23 titanium alloycitations
- 2021Electrospinning for developing flame retardant polymer materials: current status and future perspectivescitations
- 2021Thread-stripping test procedures leading to factors of safety data for friction-drilled holes in thin-section aluminium alloycitations
- 2020Reuse of grade 23 Ti6Al4V powder during the laser-based powder bed fusion processcitations
- 2017Deposit Shedding in Biomass-Fired Boilers: Shear Adhesion Strength Measurementscitations
- 2017Deposit Shedding in Biomass-Fired Boilers: Shear Adhesion Strength Measurementscitations
- 2016Adhesion Strength of Biomass Ash Deposits
- 2016Adhesion Strength of Biomass Ash Deposits
- 2016Deposit Shedding in Biomass-fired Boilers: Shear Adhesion Strength Measurements
- 2016Deposit Shedding in Biomass-fired Boilers: Shear Adhesion Strength Measurements
- 2013Deposit formation in a full-scale pulverized wood-fired power plant with and without coal fly ash addition
- 2013Modeling of sulfation of potassium chloride by ferric sulfate addition during grate-firing of biomass
- 2012Deposit Probe Measurements in Danish Grate and Pulverized Fuel Biomass Power Boilers
- 2012Deposit Probe Measurements in Danish Grate and Pulverized Fuel Biomass Power Boilers
- 2012Combustion Aerosols from Full-Scale Suspension-Firing of Wood Pellets
- 2010On the prediction of the residual fatigue life of cracked structures repaired by the stop-hole methodcitations
Places of action
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article
Investigating the Interaction between Ilmenite and Zinc for Chemical Looping
Abstract
<p>The iron and titanium oxide ilmenite is a benchmark oxygen carrier for chemical looping combustion (CLC) and oxygen carrier-aided combustion (OCAC). Both of them are combustion technologies for biomass and waste fuels with lower emissions and low costs for carbon capture. Here, the interaction between the ash component zinc and oxygen carrier ilmenite is studied in a two-staged vertical tube reactor. Three types of ilmenites─Norwegian rock ilmenite, synthesized ilmenite, and ilmenite extracted after 200 h of OCAC in a full-scale fluidized bed unit─were exposed to gas-phase Zn and ZnCl<sub>2</sub>. Following the exposure, samples were analyzed concerning morphology, chemical distribution, composition, and crystalline phases. The observations were complemented with thermodynamic equilibrium calculations. It is observed that the iron-rich layer formed on the external surface of rock ilmenite after activation promotes the reaction with both gaseous zinc compounds, with zinc ferrite formed in the external Fe-rich layer. In contrast, ilmenite with no segregation of Fe and Ti showed to interact less with zinc species. Metallic Zn penetrated the particles, while the interaction depth was shallow with ZnCl<sub>2</sub> for all investigated ilmenite oxygen carriers. The gaseous conditions, particle ash layer composition, and iron availability are shown to play an important role in the interaction between zinc compounds and ilmenite particles. Based on these results, interaction mechanisms for Zn and ZnCl<sub>2</sub> are proposed. This interaction could have environmental implications for the toxicity of ash streams from waste combustion in addition to possibilities for Zn recycling.</p>