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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Wu, Hao
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2023Investigating the Interaction between Ilmenite and Zinc for Chemical Loopingcitations
- 2023Full-scale investigations of initial deposits formation in a cement plant co-fired with coal and SRFcitations
- 2022Powder Reuse in Laser-Based Powder Bed Fusion of Ti6Al4V—Changes in Mechanical Properties during a Powder Top-Up Regimecitations
- 2022On the application of Vickers micro hardness testing to isotactic polypropylenecitations
- 2022Thermal Conversion of Sodium Phytate Using the Oxygen Carrier Ilmenite Interaction with Na-Phosphate and Its Effect on Reactivitycitations
- 2021Analysis of spatter removal by sieving during a powder-bed fusion manufacturing campaign in grade 23 titanium alloycitations
- 2021Electrospinning for developing flame retardant polymer materials: current status and future perspectivescitations
- 2021Thread-stripping test procedures leading to factors of safety data for friction-drilled holes in thin-section aluminium alloycitations
- 2020Reuse of grade 23 Ti6Al4V powder during the laser-based powder bed fusion processcitations
- 2017Deposit Shedding in Biomass-Fired Boilers: Shear Adhesion Strength Measurementscitations
- 2017Deposit Shedding in Biomass-Fired Boilers: Shear Adhesion Strength Measurementscitations
- 2016Adhesion Strength of Biomass Ash Deposits
- 2016Adhesion Strength of Biomass Ash Deposits
- 2016Deposit Shedding in Biomass-fired Boilers: Shear Adhesion Strength Measurements
- 2016Deposit Shedding in Biomass-fired Boilers: Shear Adhesion Strength Measurements
- 2013Deposit formation in a full-scale pulverized wood-fired power plant with and without coal fly ash addition
- 2013Modeling of sulfation of potassium chloride by ferric sulfate addition during grate-firing of biomass
- 2012Deposit Probe Measurements in Danish Grate and Pulverized Fuel Biomass Power Boilers
- 2012Deposit Probe Measurements in Danish Grate and Pulverized Fuel Biomass Power Boilers
- 2012Combustion Aerosols from Full-Scale Suspension-Firing of Wood Pellets
- 2010On the prediction of the residual fatigue life of cracked structures repaired by the stop-hole methodcitations
Places of action
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article
Thermal Conversion of Sodium Phytate Using the Oxygen Carrier Ilmenite Interaction with Na-Phosphate and Its Effect on Reactivity
Abstract
Chemical looping combustion (CLC) can be used to convert biomass for heat and/or power production while efficiently capturing the produced CO<sub>2</sub>. This is possible because the biomass is oxidized by an oxygen carrier instead of directly by air. However, the ash species in biomass can interact with the oxygen carrier causing agglomeration and/or reducing its reactivity. One of the ash elements previously reported to cause problems is phosphorus and especially in combination with alkali. In this work, the interaction between a benchmark oxygen carrier, ilmenite, and a phosphorus model compound, sodium phytate, was studied up to a temperature of 1100 °C in N<sub>2</sub> using a fixed bed setup. Activated carbon and NaH<sub>2</sub>PO<sub>4</sub> (thermally decomposing to NaPO<sub>3</sub>) were also used to study the individual effect of carbon and inorganic Na-phosphate. The CO and CO<sub>2</sub> concentration in the flue gas was measured to monitor the oxidation of the samples, which showed that ilmenite participated in the conversion of Na-phytate starting from about 600 °C. Scanning electron microscopy coupled with energy dispersive X-ray spectroscopy analysis of cross sections of the ilmenite residues revealed that Na-phosphate (forming from Na-phytate) penetrates porous ilmenite particles to a greater extent compared to denser particles, which may reduce the agglomeration tendencies since a lower amount of sticky Na-phosphate melt will coat the particle surface. The effect of Na-phytate on the reactivity of ilmenite was quantitatively determined in a fluidized bed using 50% syngas or CO in N<sub>2</sub>. For a loading of 1.5 wt % Na-phytate, the reactivity toward CO decreased to only 20% of the reference sample. The reason was partly attributed to a decreased surface area but is likely also due to the formation of less reactive Na–Fe-phosphates. A compilation of thermodynamic data relevant for the NaPO<sub>3</sub>–FeO<sub><i>x</i></sub> (<i>x</i> = 1 or 1.5) system shows that NaPO<sub>3</sub> can form a melt containing dissolved iron starting from around 600 °C and that sodium and phosphorus are present solely in this form above approximately 930 °C at equilibrium.