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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Marder, Seth R.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2023Additive-free molecular acceptor organic solar cells processed from a biorenewable solvent approaching 15% efficiencycitations
- 2022Controlled n‐Doping of Naphthalene‐Diimide‐Based 2D Polymerscitations
- 2022Visualisation of individual dopants in a conjugated polymer : sub-nanometre 3D spatial distribution and correlation with electrical propertiescitations
- 2022Double Doping of a Low-Ionization-Energy Polythiophene with a Molybdenum Dithiolene Complexcitations
- 2020Ruthenium pentamethylcyclopentadienyl mesitylene dimer: a sublimable n-dopant and electron buffer layer for efficient n-i-p perovskite solar cellscitations
- 2019Enhanced Thermoelectric Power Factor of Tensile Drawn Poly(3-hexylthiophene)citations
- 2019Interfacial charge-transfer doping of metal halide perovskites for high performance photovoltaicscitations
- 2017Absorption Tails of Donor:C-60 Blends Provide Insight into Thermally Activated Charge-Transfer Processes and Polaron Relaxationcitations
- 2017Molecular weight tuning of low bandgap polymers by continuous flow chemistry: increasing the applicability of PffBT4T for organic photovoltaicscitations
- 2016Phosphonic Acids for Interfacial Engineering of Transparent Conductive Oxidescitations
- 2016An Introduction to the Electronic Structure of π-Conjugated Molecules and Polymers, and to the Concept of Electronic Bands
- 2015Mechanism that governs the electro-optic response of second-order nonlinear polymers on silicon substratescitations
- 2013Physical mixtures of small-molecule and polymeric organic semiconductorscitations
- 2012Surface-initiated synthesis of poly(3-methylthiophene) from indium tin oxide and its electrochemical propertiescitations
- 2009Direct writing and characterization of poly(p -phenylene vinylene) nanostructurescitations
- 2008Reversible nanoscale local wettability modifications by thermochemical nanolithography
- 2007Analysis of improved photovoltaic properties of pentacene/C60 organic solar cellscitations
- 2007Norbornene-based copolymers with iridium complexes and bis(carbazolyl) fluorene groups in their side-chains and their use in light-emitting diodescitations
- 2007High-speed, sub-15 nm feature size thermochemical nanolithographycitations
- 2000Two-photon fluorescent labels with enhanced sensitivity for biological imaging
Places of action
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article
Phosphonic Acids for Interfacial Engineering of Transparent Conductive Oxides
Abstract
Transparent conducting oxides (TCOs), such as indium tin oxide and zinc oxide, play an important role as electrode materials in organic-semiconductor devices. The properties of the inorganic-organic interface - the offset between the TCO Fermi level and the relevant transport level, the extent to which the organic semiconductor can wet the oxide surface, and the influence of the surface on semiconductor morphology - significantly affect device performance. This review surveys the literature on TCO modification with phosphonic acids (PAs), which has increasingly been used to engineer these interfacial properties. The first part outlines the relevance of TCO surface modification to organic electronics, surveys methods for the synthesis of PAs, discusses the modes by which they can bind to TCO surfaces, and compares PAs to alternative organic surface modifiers. The next section discusses methods of PA monolayer deposition, the kinetics of monolayer formation, and structural evidence regarding molecular orientation on TCOs. The next sections discuss TCO work-function modification using PAs, tuning of TCO surface energy using PAs, and initiation of polymerizations from TCO-tethered PAs. Finally, studies that examine the use of PA-modified TCOs in organic light-emitting diodes and organic photovoltaics are compared. © 2016 American Chemical Society.