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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Tu, Min
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Topics
Publications (6/6 displayed)
- 2023Vapor-assisted synthesis of the MOF-74 metal–organic framework family from zinc, cobalt, and magnesium oxidescitations
- 2023Molecular Layer Deposition of Zeolitic Imidazolate Framework-8 Filmscitations
- 2023Molecular Layer Deposition of Zeolitic Imidazolate Framework-8 Filmscitations
- 2023Molecular Layer Deposition of Zeolitic Imidazolate Framework-8 Filmscitations
- 2020Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Large-Pore Metal-Organic Framework MAF-6citations
- 2014Self-Directed Localization of ZIF-8 Thin Film Formation by Conversion of ZnO Nanolayerscitations
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article
Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Large-Pore Metal-Organic Framework MAF-6
Abstract
<p>A simple solvent- and catalyst-free method is presented for the synthesis of the large-pore metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)<sub>2</sub>) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, crystalline films of a large-pore material could be deposited for the first time entirely from the vapor phase. A combination of positron annihilation lifetime spectroscopy (PALS) and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diameter ∼2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), pair distribution function (PDF), and extended X-ray absorption fine structure (EXAFS). The exceptional uptake capacity of MAF-6 in comparison to ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.</p>