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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Skidmore, Melissa
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (3/3 displayed)
- 2021Unconventional, Gram-Scale Synthesis of a Molecular Organic Luminogen and its Application in a Blue-Emitting OLEDcitations
- 2016Development of a high performance donor-acceptor conjugated polymer – synergy in materials and device optimizationcitations
- 2015Redox levels of a closo-osmaborane: a density functional theory, electron paramagnetic resonance and electrochemical studycitations
Places of action
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article
Development of a high performance donor-acceptor conjugated polymer – synergy in materials and device optimization
Abstract
The development of a high-performance polymer PBDT-BT for bulk heterojunction solar cell devices is summarized. The polymer was first synthesized by Stille polycondensation, and solar cell devices in conventional geometry were optimized through the use of a lithium salt cathode interlayer reaching 6% power conversion efficiency. Improvements were made to the synthesis of the polymer using Suzuki polycondensation giving high-molecularweight material in the Mn = 100 kg/mol range. Further device optimization in inverted geometry gave power conversion efficiency of over 9%. The synthesis scalability as well as the batch-to-batch reproducibility of the polymer were extensively investigated.