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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Friedrich, Dennis
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Resolving electron and hole transport properties in semiconductor materials by constant light-induced magneto transportcitations
- 2024Unraveling electron dynamics in p‑type indium phosphide (100): a time-resolved two-photon photoemission study
- 2024Integration of Multijunction Absorbers and Catalysts for Efficient Solar‐Driven Artificial Leaf Structures: A Physical and Materials Science Perspectivecitations
- 2024Resolving electron and hole transport properties in semiconductor materials by constant light-induced magneto transport.
- 2022Predicting Solar Cell Performance from Terahertz and Microwave Spectroscopycitations
- 2022Predicting solar cell performance from terahertz and microwave spectroscopycitations
- 2020Grain Boundaries Limit the Charge Carrier Transport in Pulsed Laser Deposited α-SnWO4 Thin Film Photoabsorberscitations
- 2018Charge carrier lifetimes in Cr-Fe-Al-O thin filmscitations
- 2018Formation and suppression of defects during heat treatment of BiVO4 photoanodes for solar water splittingcitations
- 2017Enhancing Charge Carrier Lifetime in Metal Oxide Photoelectrodes through Mild Hydrogen Treatmentcitations
- 2016Comprehensive Evaluation of CuBi2O4 as a Photocathode Material for Photoelectrochemical Water Splittingcitations
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article
Comprehensive Evaluation of CuBi2O4 as a Photocathode Material for Photoelectrochemical Water Splitting
Abstract
CuBi<sub>2</sub>O<sub>4</sub> is a multinary p-type semiconductor that has recently been identified as a promising photocathode material for photoelectrochemical (PEC) water splitting. It has an optimal bandgap energy (∼1.8 eV) and an exceptionally positive photocurrent onset potential (>1 V vs RHE), making it an ideal candidate for the top absorber in a dual absorber PEC device. However, photocathodes made from CuBi<sub>2</sub>O<sub>4</sub> have not yet demonstrated high photoconversion efficiencies, and the factors that limit the efficiency have not yet been fully identified. In this work we characterize CuBi<sub>2</sub>O<sub>4</sub> photocathodes synthesized by a straightforward drop-casting procedure and for the first time report many of the quintessential material properties that are relevant to PEC water splitting. Our results provide important insights into the limitations of CuBi<sub>2</sub>O<sub>4</sub> in regards to optical absorption, charge carrier transport, reaction kinetics, and stability. This information will be valuable in future work to optimize CuBi<sub>2</sub>O<sub>4</sub> as a PEC material. In addition, we report new benchmark photocurrent density and IPCE values for CuBi<sub>2</sub>O<sub>4</sub> photocathodes. © 2016 American Chemical Society.