| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Caruso, Frank
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2023Protease-Responsive Hydrogel Microparticles for Intradermal Drug Deliverycitations
- 2020Protein Component of Oyster Glycogen Nanoparticlescitations
- 2019The future of layer-by-layer assembly: A tribute to ACS Nano associate editor Helmuth Möhwaldcitations
- 2019Glycogen as a building block for advanced biological materialscitations
- 2018Metal-Organic Frameworks for Cell and Virus Biologycitations
- 2015Surface-Confined Amorphous Films from Metal-Coordinated Simple Phenolic Ligandscitations
- 2015Nanoporous Metal-Phenolic Particles as Ultrasound Imaging Probes for Hydrogen Peroxide.citations
- 2014Tuning particle biodegradation through polymer-peptide blend compositioncitations
- 2012Tailoring the Chain Packing in Ultrathin Polyelectrolyte Films Formed by Sequential Adsorptioncitations
- 2012Synthesis and functionalization of nanoengineered materials using click chemistrycitations
- 2012Engineering cellular degradation of multilayered capsules through controlled cross-linkingcitations
- 2011Nanoengineered films via surface-confined continuous assembly of polymerscitations
- 2009Cholesterol-mediated anchoring of enzyme-loaded liposomes within disulfide-stabilized polymer carrier capsulescitations
- 2009Tuning the formation and degradation of layer-by-layer assembled polymer hydrogel microcapsulescitations
- 2009Stabilization and functionalization of polymer multilayers and capsules via thiol-ene click chemistrycitations
- 2005Optical Properties of Nanoparticle-based Metallodielectric Inverse Opalscitations
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article
Surface-Confined Amorphous Films from Metal-Coordinated Simple Phenolic Ligands
Abstract
<p>Coordination chemistry of natural polyphenols and transition metals allows rapid self-assembly of conformal coatings on diverse substrates. Herein, we report that this coordination-driven self-assembly process applies to simple phenolic molecules with monotopic or ditopic chelating sites (as opposed to macromolecular, multitopic polyphenols), leading to surface-confined amorphous films upon metal coordination. Films fabricated from gallic acid, pyrogallol, and pyrocatechol, which are the major monomeric building blocks of polyphenols, have been studied in detail. Pyrocatechol, with one vicinal diol group (i.e., bidentate), has been observed to be the limiting case for such assembly. This study expands the toolbox of available phenolic ligands for the formation of surface-confined amorphous films, which may find application in catalysis, energy, optoelectronics, and the biomedical sciences.</p>