| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Feyter, Steven De
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Topics
Publications (13/13 displayed)
- 2024Reversible Redox‐Driven Crystallization in a Paracyclophane Monolayer at a Solid–Liquid Interfacecitations
- 2024Upscaled Synthesis Protocol for Phase-Pure, Colloidally Stable MXenes with Long Shelf Livescitations
- 2024Single-Layered Imine-Linked Porphyrin-Based Two-Dimensional Covalent Organic Frameworks Targeting CO<sub>2</sub> Reductioncitations
- 2023Molecular Layer Deposition of Zeolitic Imidazolate Framework-8 Filmscitations
- 2023Curved graphene nanoribbons derived from tetrahydropyrene-based polyphenylenes via one-pot K-region oxidation and Scholl cyclizationcitations
- 2022An embedded interfacial network stabilizes inorganic CsPbI3 perovskite thin filmscitations
- 2021Two-dimensional perovskites with alternating cations in the interlayer space for stable light-emitting diodescitations
- 2019Integrated Cleanroom Process for the Vapor-Phase Deposition of Large-Area Zeolitic Imidazolate Framework Thin Filmscitations
- 2018Hydrogen-bonded siloxane liquid crystals for hybrid nanomaterials
- 2016Liquid nickel salts: synthesis, crystal structure determination and electrochemical synthesis of nickel nanoparticles
- 2014Layer-by-Layer synthesis and tunable optical properties of hybrid magnetic-plasmonic nanocomposites using short bifunctional molecular linkerscitations
- 2006Chiral alignment of OPV chromophores: explitation of the ureidophtalimide based foldamer
- 2003Morphology of protein polymer hybrid films studied by AFM and scanning confocal fluorescence microscopy
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article
Molecular Layer Deposition of Zeolitic Imidazolate Framework-8 Films
Abstract
<p>Vapor-phase film deposition of metal-organic frameworks (MOFs) would facilitate the integration of these materials into electronic devices. We studied the vapor-phase layer-by-layer deposition of zeolitic imidazolate framework 8 (ZIF-8) by consecutive, self-saturating reactions of diethyl zinc, water, and 2-methylimidazole on a substrate. Two approaches were compared: (1) Direct ZIF-8 “molecular layer deposition” (MLD), which enables a nanometer-resolution thickness control and employs only self-saturating reactions, resulting in smooth films that are crystalline as-deposited, and (2) two-step ZIF-8 MLD, in which crystallization occurs during a postdeposition treatment with additional linker vapor. The latter approach resulted in a reduced deposition time and an improved MOF quality, i.e., increased crystallinity and probe molecule uptake, although the smoothness and thickness control were partially lost. Both approaches were developed in a modified atomic layer deposition reactor to ensure cleanroom compatibility.</p>