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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gibbs, Alexandra S.
ISIS Neutron and Muon Source
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022The crystal and defect structures of polar KBiNb 2 O 7
- 2022Low-intermediate-temperature, high-pressure thermoelastic and crystallographic properties of thermoelectric clausthalite (PbSe-I)citations
- 2022Competing spin-orbital singlet states in the 4d4 honeycomb ruthenate Ag3LiRu2O6citations
- 2022The crystal and defect structures of polar KBiNb2O7
- 2021Disorder-induced structural complexity in the barlowite family of S = 1/2 kagomé magnetscitations
- 2021Disentangling the phase sequence and correlated critical properties in Bi0.7La0.3FeO3 by structural studiescitations
- 2019Pressure-induced collapse of the spin-orbital Mott state in the hyperhoneycomb iridate β-Li2IrO3citations
- 2017Cation disorder and phase transitions in the structurally complex solar cell material Cu2ZnSnS4citations
- 2017Robust Bain distortion in the premartensite phase of a platinum-substituted Ni2MnGa magnetic shape memory alloycitations
- 2011High-temperature phase transitions of hexagonal YMnO3citations
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article
Disorder-induced structural complexity in the barlowite family of S = 1/2 kagomé magnets
Abstract
We present a comprehensive structural and magnetic characterization of the barlowite family of S = 1/2 kagomé magnets, Cu<sub>4</sub>(OH)<sub>6</sub>FX, where X = Cl, Br, or I. Through high-resolution synchrotron X-ray and neutron powder diffraction measurements, we reveal two sources of structural complexity within this family of materials, namely, compositional disorder of the halide species that occupy sites in between the kagomé layers and the positional disorder of the interlayer Cu<sup>2+</sup> ions that persists well into the <i>Pnma</i> structural ground state. We demonstrate that understanding these inherent structural disorders is key as they correlate with the degree of partial order in the magnetic ground states of these quantum frustrated magnets.