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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Manna, Liberato
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (61/61 displayed)
- 2024Investigation of the Octahedral Network Structure in Formamidinium Lead Bromide Nanocrystals by Low-Dose Scanning Transmission Electron Microscopycitations
- 2024Investigation of the octahedral network structure in formamidinium lead bromide nanocrystals by low-dose scanning transmission electron microscopycitations
- 2024Exogenous Metal Cations in the Synthesis of CsPbBr3 Nanocrystals and Their Interplay with Tertiary Aminescitations
- 2024Exogenous Metal Cations in the Synthesis of CsPbBr3 Nanocrystals and Their Interplay with Tertiary Aminescitations
- 2024Stainless Steel Activation for Efficient Alkaline Oxygen Evolution in Advanced Electrolyzerscitations
- 2024Lead‐free halide perovskite materials and optoelectronic devices: progress and prospectivecitations
- 2024Exciton-photocarrier interference in mixed lead-halide-perovskite nanocrystals
- 2023Collective Diffraction Effects in Perovskite Nanocrystal Superlatticescitations
- 2023Lead-Free Halide Perovskite Materials and Optoelectronic Devices: Progress and Prospectivecitations
- 2023State of the Art and Prospects for Halide Perovskite Nanocrystals.
- 2023Light Emission from Low‐Dimensional Pb‐Free Perovskite‐Related Metal Halide Nanocrystalscitations
- 2023Lead‐Free Halide Perovskite Materials and Optoelectronic Devices: Progress and Prospectivecitations
- 2022Recent Progress in Mixed A‐Site Cation Halide Perovskite Thin‐Films and Nanocrystals for Solar Cells and Light‐Emitting Diodescitations
- 2022Recent Progress in Mixed A‐Site Cation Halide Perovskite Thin‐Films and Nanocrystals for Solar Cells and Light‐Emitting Diodes
- 2022Halide perovskites as disposable epitaxial templates for the phase-selective synthesis of lead sulfochloride nanocrystalscitations
- 2022Recent progress in mixed a‐site cation halide perovskite thin‐films and nanocrystals for solar cells and light‐emitting diodescitations
- 2022One Hundred-Nanometer-Sized CsPbBr3/m-SiO2 Composites Prepared via Molten-Salts Synthesis are Optimal Green Phosphors for LCD Display Devicescitations
- 2022Exploiting the Transformative Features of Metal Halides for the Synthesis of CsPbBr3@SiO2 Core-Shell Nanocrystalscitations
- 2022Highly Emitting Perovskite Nanocrystals with 2-Year Stability in Water through an Automated Polymer Encapsulation for Bioimagingcitations
- 2022Cu+→ Mn2+ Energy Transfer in Cu, Mn Coalloyed Cs3ZnCl5Colloidal Nanocrystalscitations
- 2021Detection of Pb2+traces in dispersion of Cs4PbBr6 nanocrystals by in situ liquid cell transmission electron microscopycitations
- 2021Structure and Surface Passivation of Ultrathin Cesium Lead Halide Nanoplatelets Revealed by Multilayer Diffractioncitations
- 2021Metamorphoses of Cesium Lead Halide Nanocrystalscitations
- 2021Sb-Doped Metal Halide Nanocrystals: A 0D versus 3D Comparisoncitations
- 2021Halide Perovskite-Lead Chalcohalide Nanocrystal Heterostructurescitations
- 2021Halide Perovskite-Lead Chalcohalide Nanocrystal Heterostructurescitations
- 2021Exploiting the Transformative Features of Metal Halides for the Synthesis of CsPbBr3@SiO2 Core–Shell Nanocrystalscitations
- 2021State of the art and prospects for halide perovskite nanocrystalscitations
- 2020Superlattices are greener on the other sidecitations
- 2020Alloy CsCd x Pb 1- x Br 3 Perovskite Nanocrystals:The Role of Surface Passivation in Preserving Composition and Blue Emissioncitations
- 2020CsPbX3/SiOx (X = Cl, Br, I) monoliths prepared via a novel sol-gel route starting from Cs4PbX6 nanocrystalscitations
- 2020Microwave-Induced Structural Engineering and Pt Trapping in 6R-TaS2 for the Hydrogen Evolution Reactioncitations
- 2020Transforming colloidal Cs4PbBr6 nanocrystals with poly(maleic anhydride-alt-1-octadecene) into stable CsPbBr3 perovskite emitters through intermediate heterostructurescitations
- 2020Nanocrystals of Lead Chalcohalides:A Series of Kinetically Trapped Metastable Nanostructurescitations
- 2020Alloy CsCd x Pb1-x Br3 Perovskite Nanocrystals: The Role of Surface Passivation in Preserving Composition and Blue Emissioncitations
- 2020Alloy CsCd xPb1- xBr3Perovskite Nanocrystalscitations
- 2020Nano- and microscale apertures in metal films fabricated by colloidal lithography with perovskite nanocrystalscitations
- 2020Developing Lattice Matched ZnMgSe Shells on InZnP Quantum Dots for Phosphor Applicationscitations
- 2020Efficient, fast and reabsorption-free perovskite nanocrystal-based sensitized plastic scintillatorscitations
- 2020Nanocrystals of Lead Chalcohalidescitations
- 2020Cs 3 Cu 4 In 2 Cl 13 Nanocrystals:A Perovskite-Related Structure with Inorganic Clusters at A Sitescitations
- 2020Cs3Cu4In2Cl13 Nanocrystalscitations
- 2019Ruthenium-Decorated Cobalt Selenide Nanocrystals for Hydrogen Evolutioncitations
- 2019Fully Inorganic Ruddlesden-Popper Double Cl-I and Triple Cl-Br-I Lead Halide Perovskite Nanocrystalscitations
- 2019Coating evaporated MAPI thin films with organic molecules: improved stability at high temperature and implementation in high-efficiency solar cellscitations
- 2019Stable Ligand Coordination at the Surface of Colloidal CsPbBr 3 Nanocrystalscitations
- 2019Stable Ligand Coordination at the Surface of Colloidal CsPbBr3 Nanocrystalscitations
- 2019In situ transmission electron microscopy study of electron beam-induced transformations in colloidal cesium lead halide perovskite nanocrystalscitations
- 2018Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystalscitations
- 2018Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystalscitations
- 2018In Situ Dynamic Nanostructuring of the Cu–Ti Catalyst-Support System Promotes Hydrogen Evolution under Alkaline Conditionscitations
- 2018Benzoyl Halides as Alternative Precursors for the Colloidal Synthesis of Lead-Based Halide Perovskite Nanocrystalscitations
- 2018Ab initio structure determination of Cu2- xTe plasmonic nanocrystals by precession-assisted electron diffraction tomography and HAADF-STEM imagingcitations
- 2018The Phosphine Oxide Route toward Lead Halide Perovskite Nanocrystalscitations
- 2018Ab Initio Structure Determination of Cu2- xTe Plasmonic Nanocrystals by Precession-Assisted Electron Diffraction Tomography and HAADF-STEM Imagingcitations
- 2016Tuning the Lattice Parameter of InxZnyP for Highly Luminescent Lattice-Matched Core/Shell Quantum Dots
- 2015Prospects of Nanoscience with Nanocrystalscitations
- 2014Self-assembly of octapod-shaped colloidal nanocrystals into a hexagonal ballerina network embedded in a thin polymer film
- 2013Single-mode tunable laser emission in the single-exciton regime from colloidal nanocrystalscitations
- 2012Colloidal Cu 2-x(S ySe 1-y) alloy nanocrystals with controllable crystal phase: Synthesis, plasmonic properties, cation exchange and electrochemical lithiation
- 2009Quantum dot nanoparticles: Properties, surface functionalization, and their applications in biosensoring and imaging
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article
Alloy CsCd xPb1- xBr3Perovskite Nanocrystals
Abstract
<p>Various strategies have been proposed to engineer the band gap of metal halide perovskite nanocrystals (NCs) while preserving their structure and composition and thus ensuring spectral stability of the emission color. An aspect that has only been marginally investigated is how the type of surface passivation influences the structural/color stability of AMX3 perovskite NCs composed of two different M2+ cations. Here, we report the synthesis of blue-emitting Cs-oleate capped CsCdxPb1-xBr3 NCs, which exhibit a cubic perovskite phase containing Cd-rich domains of Ruddlesden-Popper phases (RP phases). The RP domains spontaneously transform into pure orthorhombic perovskite ones upon NC aging, and the emission color of the NCs shifts from blue to green over days. On the other hand, postsynthesis ligand exchange with various Cs-carboxylate or ammonium bromide salts, right after NC synthesis, provides monocrystalline NCs with cubic phase, highlighting the metastability of RP domains. When NCs are treated with Cs-carboxylates (including Cs-oleate), most of the Cd2+ ions are expelled from NCs upon aging, and the NCs phase evolves from cubic to orthorhombic and their emission color changes from blue to green. Instead, when NCs are coated with ammonium bromides, the loss of Cd2+ ions is suppressed and the NCs tend to retain their blue emission (both in colloidal dispersions and in electroluminescent devices), as well as their cubic phase, over time. The improved compositional and structural stability in the latter cases is ascribed to the saturation of surface vacancies, which may act as channels for the expulsion of Cd2+ ions from NCs. </p>